{"id":"W2157796153","doi":"10.1039/b110927h","title":"Mixed nitrosyl/phosphinidene and nitrene/phosphinidene clusters of rutheniumElectronic supplementary information (ESI) available: experimental, preparation of compounds. See http://www.rsc.org/suppdata/cc/b1/b110927h","year":2002,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; Steacie Institute for Molecular Sciences","funders":"","keywords":"Phosphinidene; Nitrene; Chemistry; Triflic acid; Cluster (spacecraft); Stereochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000169807,0.0003283378,0.0003134831,0.0002008446,0.000220933,0.0002884978,0.0005904337,0.0002586312,0.003529144],"category_scores_gemma":[0.0002194475,0.0002488232,0.0001555644,0.0001917453,0.0001391541,0.0003121211,0.0003505738,0.0003892562,0.0006898998],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006735509,"about_ca_system_score_gemma":0.000215439,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000783699,"about_ca_topic_score_gemma":0.002344335,"domain_scores_codex":[0.9997846,0.00002143069,0.00001019524,0.00007525029,0.00006589091,0.00004256047],"domain_scores_gemma":[0.9998919,0.00001832006,0.00002167511,0.00001721255,0.00002359509,0.0000273017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00019049,0.00001972551,0.00008719456,0.0001000587,0.00001433568,0.00005295673,0.00002875278,0.0002954951,0.997331,0.0004396973,0.0002419347,0.001198313],"study_design_scores_gemma":[0.00002097874,0.0001405373,0.0004506346,0.00000370824,0.00001114838,0.00005705061,0.000008166096,0.001031803,0.9966092,0.00003368456,0.0016284,0.000004611803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901069,0.0007468,0.002779688,0.00005360474,0.00003323629,0.00005195103,0.0003947564,0.0001436319,0.005689358],"genre_scores_gemma":[0.9900072,0.0002364221,0.003289681,0.00001850394,0.000008741928,0.00005286748,0.0006783779,0.00006280493,0.005645494],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003529144,"threshold_uncertainty_score":0.01180613,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03243686000331423,"score_gpt":0.2552149401590173,"score_spread":0.2227780801557031,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}