{"id":"W2157917031","doi":"10.1002/anie.201108779","title":"A Formal Synthesis of Vinigrol","year":2012,"lang":"de","type":"article","venue":"Angewandte Chemie International Edition","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Key (lock); Intramolecular force; Computer science; Core (optical fiber); Claisen rearrangement; Product (mathematics); Natural product; Chemistry; Combinatorial chemistry; Stereochemistry; Mathematics; Computer security","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001462302,0.000584665,0.000294988,0.0004963874,0.0003406691,0.0005200518,0.0005064126,0.000271867,0.00965592],"category_scores_gemma":[0.0001969785,0.0002274503,0.0002708002,0.0003647655,0.0004615179,0.0004737636,0.0008609938,0.0009924169,0.003482814],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005510731,"about_ca_system_score_gemma":0.0006894437,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006171668,"about_ca_topic_score_gemma":0.000955791,"domain_scores_codex":[0.999809,0.0000150619,0.00001507929,0.00005204053,0.00004272515,0.00006614082],"domain_scores_gemma":[0.9999505,0.000005517589,0.000004904432,0.00001268506,0.00001099456,0.00001541578],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001521233,0.0002968711,0.0003272191,0.001393896,0.00005553932,0.002143156,0.0009601851,0.004208653,0.6021957,0.23246,0.007615244,0.1481915],"study_design_scores_gemma":[0.0001096801,0.001171064,0.0006166332,0.000157728,0.00005247039,0.001638429,0.0002645972,0.002565081,0.5987788,0.02570374,0.368848,0.00009373914],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4140943,0.01070724,0.264993,0.002744716,0.004156095,0.001137797,0.004571707,0.002784887,0.2948103],"genre_scores_gemma":[0.889712,0.006317509,0.06051797,0.0003203379,0.0001273673,0.000214794,0.001562443,0.0002464669,0.04098101],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00965592,"threshold_uncertainty_score":0.03230226,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01540011347799841,"score_gpt":0.2585214373946159,"score_spread":0.2431213239166175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}