{"id":"W2157940487","doi":"10.1002/chem.201002542","title":"One‐, Two‐ and Three‐Periodic Metal–Organic Rotaxane Frameworks (MORFs): Linking Cationic Transition‐Metal Nodes with an Anionic Rotaxane Ligand","year":2010,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Rotaxane; Cationic polymerization; Ligand (biochemistry); Metal-organic framework; Metal; Transition metal; Chemistry; Crystallography; Materials science; Stereochemistry; Supramolecular chemistry; Polymer chemistry; Receptor; Organic chemistry; Crystal structure; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009563197,0.000569613,0.0005767462,0.00006492271,0.00109374,0.000810585,0.0008285065,0.0003663019,0.005555681],"category_scores_gemma":[0.0001717191,0.0005313523,0.0001990771,0.0003470654,0.0004374821,0.0004362661,0.0001116865,0.004241581,0.00007309882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007150164,"about_ca_system_score_gemma":0.0002291281,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006740648,"about_ca_topic_score_gemma":0.00002217416,"domain_scores_codex":[0.9969998,0.0001007662,0.0008428993,0.0008237658,0.0005739804,0.0006588003],"domain_scores_gemma":[0.9971582,0.0001275367,0.0006473188,0.001120053,0.0002551385,0.0006917309],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005461357,0.0003115486,0.0002816114,0.000131012,0.0002285511,0.00007491207,0.0003968178,0.00003668283,0.9860052,0.00008566925,0.00001835395,0.01237495],"study_design_scores_gemma":[0.00437001,0.0002011046,0.00315226,0.001481908,0.001466302,0.01009986,0.001132428,0.00556133,0.9622008,0.002060211,0.00579582,0.002477968],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865165,0.0007660424,0.008607736,0.0008803462,0.00009596803,0.0001356452,0.00003333366,0.00018051,0.002783916],"genre_scores_gemma":[0.9878735,0.0002226423,0.009169659,0.0001702826,0.001883953,0.00002260699,0.0001011033,0.0001946547,0.0003616151],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02380448,"threshold_uncertainty_score":0.9997138,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01162650216325082,"score_gpt":0.2190676303432124,"score_spread":0.2074411281799616,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}