{"id":"W2158844036","doi":"10.1002/chem.200701322","title":"Stereoselective Isomerisation of N‐Allyl Aziridines into Geometrically Stable <i>Z</i> Enamines by Using Rhodium Hydride Catalysis","year":2007,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Isomerization; Rhodium; Chemistry; Hydride; Stereoselectivity; Medicinal chemistry; Catalysis; Selectivity; Reductive elimination; Stereochemistry; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001510522,0.0003338378,0.0001544342,0.0001361765,0.00009014189,0.0002143258,0.0003188626,0.0001653974,0.001054464],"category_scores_gemma":[0.0001601313,0.0001387786,0.0001959534,0.0001035179,0.000186669,0.000237597,0.0002250618,0.0003570476,0.0005017225],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002017295,"about_ca_system_score_gemma":0.0001752386,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004903359,"about_ca_topic_score_gemma":0.0008938939,"domain_scores_codex":[0.9998766,0.00002373479,0.00001216301,0.00003019298,0.00002358609,0.00003368809],"domain_scores_gemma":[0.9999366,0.00001011931,0.0000226004,0.00001255637,0.000007570519,0.00001041855],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001010009,0.00002335907,0.0001723924,0.00006571504,0.00001508006,0.0001621737,0.00005875622,0.0002694913,0.9924628,0.001050783,0.00009565942,0.005522922],"study_design_scores_gemma":[0.0000120703,0.0001415853,0.0003678311,0.000001912263,0.000007453024,0.0002110424,0.00001426497,0.000448851,0.9971924,0.00006470124,0.001532915,0.000004787006],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9712683,0.0008706092,0.0125863,0.00009314513,0.00003936204,0.00007755197,0.0001640454,0.0001860208,0.01471463],"genre_scores_gemma":[0.9936517,0.0004470948,0.003995783,0.00002953424,0.000006045253,0.00001188773,0.0001200871,0.00002741795,0.00171033],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001054464,"threshold_uncertainty_score":0.003527522,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01254200862374464,"score_gpt":0.2344330249447579,"score_spread":0.2218910163210133,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}