{"id":"W2159149981","doi":"10.1139/v04-153","title":"Synthesis and characterization of a series of 4-methyl-1-[2-aryl-1-diazenyl]-1,4-diazepanes and 1,4-di-[2-aryl-1-diazenyl]-1,4-diazepanes","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and pharmacology of benzodiazepine derivatives","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Chemistry; Aryl; Triazene; Proton NMR; Carbon-13 NMR; Salt (chemistry); Nuclear magnetic resonance spectroscopy; Stereochemistry; Crystallography; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001058304,0.0002249476,0.0001666015,0.0002274459,0.00008816914,0.0001354559,0.0001844746,0.0001682822,0.0008944277],"category_scores_gemma":[0.0001821454,0.00009542392,0.0001193095,0.0002122222,0.00012746,0.0002175745,0.0001205867,0.000268895,0.0003907107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001173271,"about_ca_system_score_gemma":0.0001942048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002168616,"about_ca_topic_score_gemma":0.0004693949,"domain_scores_codex":[0.9999293,0.000009523531,0.000006228203,0.00001274026,0.0000328745,0.00000928698],"domain_scores_gemma":[0.9998897,0.00001205255,0.00003352751,0.00001246651,0.0000295171,0.00002266565],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001899131,0.00001272687,0.0000593481,0.00002407947,0.000001827236,0.00001743869,0.000006827899,0.00004884025,0.9985729,0.00001818082,0.000008709004,0.001210067],"study_design_scores_gemma":[0.000007988425,0.0003862108,0.001230617,0.000002724119,0.000008328572,0.0001641788,0.00001307063,0.0002126515,0.9963441,0.00001454404,0.001612497,0.000003164627],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9872656,0.001761154,0.008706162,0.00006034572,0.0000146043,0.0001009553,0.0004517533,0.00007006156,0.00156947],"genre_scores_gemma":[0.9760291,0.002310715,0.01591833,0.00004207595,0.00001389773,0.0001206056,0.001195541,0.00003316941,0.00433665],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008944277,"threshold_uncertainty_score":0.002992153,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01063279974320421,"score_gpt":0.2134812707806591,"score_spread":0.2028484710374548,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}