{"id":"W2159327979","doi":"10.1002/chin.200726154","title":"Synthesis of the Sesquiterpenoid Lactarane Skeleton by a Radical Cyclobutylcarbinyl/Cyclopropylcarbinyl Fragmentation Sequence.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Fragmentation (computing); Sequence (biology); Skeleton (computer programming); Stereochemistry; Combinatorial chemistry; Programming language; Biochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002874463,0.0002819915,0.0003267872,0.00004524445,0.0001233361,0.00002768281,0.000635721,0.000346158,0.001475361],"category_scores_gemma":[0.0008062783,0.0002166379,0.0002690602,0.0003559842,0.0004781655,0.0001922276,0.0001160177,0.000519575,0.00003230369],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004623721,"about_ca_system_score_gemma":0.0001103768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00020081,"about_ca_topic_score_gemma":0.000007283847,"domain_scores_codex":[0.9977165,0.000001273614,0.0007001468,0.0003250309,0.0007325652,0.0005244646],"domain_scores_gemma":[0.9981582,0.0005293103,0.0003306578,0.0006478272,0.00007741252,0.000256646],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006539965,0.0001153347,0.000244262,0.0001410691,0.00004989791,0.000003176632,0.0001583703,4.42341e-7,0.9379575,0.00008014709,0.008507598,0.05267678],"study_design_scores_gemma":[0.0003562808,0.000009273515,0.0001264959,0.0001224839,0.00005951163,0.00002783455,0.0001953463,0.00003486366,0.9552626,0.0001958905,0.0433751,0.0002343135],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6043364,0.00006323139,0.00001200041,0.000311162,0.00008756467,0.0001716665,0.00007993064,0.00009227311,0.3948458],"genre_scores_gemma":[0.9955595,0.00003478142,0.000129104,0.0002766157,0.0001236383,0.00006823832,0.0000708827,0.00003748818,0.003699718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3912231,"threshold_uncertainty_score":0.9994375,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009178863992194896,"score_gpt":0.2511257480610053,"score_spread":0.2419468840688105,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}