{"id":"W2160549064","doi":"10.1139/v08-014","title":"The Strecker reaction — an examination in terms of no-barrier theory","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Strecker amino acid synthesis; Iminium; Reaction rate constant; Equilibrium constant; Methylamine; Computational chemistry; Reaction rate; Chemical equilibrium; Dimethylamine; Benzaldehyde; Physical chemistry; Thermodynamics; Organic chemistry; Kinetics; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00041815,0.0001155109,0.000164751,0.00004758358,0.00009505476,0.00001702504,0.0002886216,0.0001741317,0.0007291539],"category_scores_gemma":[0.000754223,0.00009655755,0.0000862608,0.0001025539,0.0001586352,0.0001776487,0.000007174611,0.0004447613,0.000004095055],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003660929,"about_ca_system_score_gemma":0.0005114071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000201764,"about_ca_topic_score_gemma":0.0004803217,"domain_scores_codex":[0.9989562,0.00002497134,0.000447409,0.000118237,0.0002310586,0.0002221143],"domain_scores_gemma":[0.9986439,0.0001439012,0.0003637308,0.0002611925,0.0001906373,0.0003966766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003315583,0.00001964414,0.0009450451,0.00002837986,0.00001511468,0.00006342585,0.0002278866,0.000003699865,0.9922616,0.00003981471,0.0001592596,0.006203002],"study_design_scores_gemma":[0.0003781856,0.00001245814,0.001347022,0.00007427529,0.00000941548,0.0003740291,0.0004434583,0.00002123855,0.9908131,0.001124875,0.005298755,0.0001032397],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9683052,0.00007627114,0.00001254888,0.00004213912,0.0001120612,0.00001772847,0.00001213984,0.000004713218,0.03141716],"genre_scores_gemma":[0.9972236,0.000047319,0.0000485859,0.00001893223,0.000246187,0.000002026502,0.000009762324,0.00001753209,0.002386115],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02903104,"threshold_uncertainty_score":0.7983723,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01033434628163206,"score_gpt":0.2117288450370266,"score_spread":0.2013944987553945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}