{"id":"W2161061779","doi":"10.1002/jrs.2419","title":"Vibrational spectroscopy study of hydrothermally produced scorodite (FeAsO<sub>4</sub>·2H<sub>2</sub>O), ferric arsenate sub‐hydrate (FAsH; FeAsO<sub>4</sub>·0.75H<sub>2</sub>O) and basic ferric arsenate sulfate (BFAS; Fe[(AsO<sub>4</sub>)<sub>1−<i>x</i></sub>(SO<sub>4</sub>)<sub><i>x</i></sub>(OH)<sub><i>x</i></sub>]·<i>w</i>H<sub>2</sub>O)","year":2009,"lang":"en","type":"article","venue":"Journal of Raman Spectroscopy","topic":"Arsenic contamination and mitigation","field":"Environmental Science","cited_by":78,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; Canadian Light Source (Canada); McGill University","funders":"","keywords":"Arsenate; Raman spectroscopy; Chemistry; Ferric; Arsenic; Hydrate; Infrared spectroscopy; Sulfate; Inorganic chemistry; Analytical Chemistry (journal); Hydrothermal circulation; Mineralogy; Crystallography; Geology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006842522,0.0001336354,0.00008868232,0.0001402729,0.000115173,0.0001226718,0.0001199468,0.0001655675,0.0005936482],"category_scores_gemma":[0.0001176407,0.00009534788,0.00009460776,0.0001112956,0.0001951232,0.00009942294,0.00008616121,0.0001646043,0.00007186856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001264648,"about_ca_system_score_gemma":0.0001036459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008710464,"about_ca_topic_score_gemma":0.001354467,"domain_scores_codex":[0.999964,0.000003981541,0.000001698614,0.000007003314,0.00001573115,0.000007642047],"domain_scores_gemma":[0.9999475,0.00001158053,0.00001331281,0.000002839864,0.00001472683,0.000009941012],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003423846,0.000005004209,0.0003106281,0.00001211157,0.000001605907,0.00001503398,0.00002350102,0.00008083289,0.9990408,0.00003753841,0.000008605991,0.0004301648],"study_design_scores_gemma":[0.00000920909,0.0001823117,0.01218548,0.00000373952,0.000006679029,0.00005620293,0.0001185701,0.002214764,0.9845231,0.00003766473,0.0006561354,0.000006229138],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990997,0.00006921603,0.0004063814,0.0000106041,0.000002720108,0.000002692523,0.00003788676,0.000007724357,0.0003630446],"genre_scores_gemma":[0.9987827,0.00006776377,0.0006470851,0.000006711045,0.000001334538,0.00000423665,0.00007378818,0.000003421556,0.0004130843],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008710464,"threshold_uncertainty_score":0.001986027,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007956353386510177,"score_gpt":0.2222818018091421,"score_spread":0.2143254484226319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}