{"id":"W2161271643","doi":"10.1139/v03-214","title":"A new family of N<i><sub>x</sub></i>O<i><sub>y</sub></i> pyridine-containing macrocycles: Synthesis and characterization of their Y(III), Ln(III), Zn(II), and Cd(II) coordination compounds","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Methylamine; Pyridine; Imine; Ligand (biochemistry); Imidazole; Protonation; Salicylaldehyde; Amine gas treating; Schiff base; Lanthanide; Stereochemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004720795,0.0003204613,0.0008967047,0.0001888883,0.0002303026,0.0000560137,0.0001878966,0.0002038137,0.00002418643],"category_scores_gemma":[0.0001875726,0.000286846,0.0001805882,0.0002288106,0.0002796978,0.0002660764,0.00004810175,0.0003192277,4.962383e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001703722,"about_ca_system_score_gemma":0.001248669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005798856,"about_ca_topic_score_gemma":0.0003295058,"domain_scores_codex":[0.9980856,0.000045453,0.0009310359,0.0002623677,0.0003211531,0.0003544313],"domain_scores_gemma":[0.9976857,0.0001085379,0.0008084203,0.0002506616,0.0004212259,0.0007254156],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003195069,0.00003755422,0.001349066,0.0003570627,0.0001842916,0.00002747379,0.001537997,0.000006361225,0.9848173,0.00002233079,0.0001293264,0.01121178],"study_design_scores_gemma":[0.001683448,0.0002691042,0.009273705,0.001550707,0.0001927052,0.0005437303,0.000827234,0.00002592731,0.9843448,0.0001558067,0.0008818371,0.0002510364],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995933,0.002108448,0.000187331,0.0008095506,0.00009393716,0.0001673893,0.00006236246,0.00001065858,0.0006273094],"genre_scores_gemma":[0.9986728,0.0006210668,0.0001758397,0.0001928383,0.0002361297,0.000004784425,0.00002447623,0.00004496421,0.00002712724],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01096074,"threshold_uncertainty_score":0.9999584,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01568909454859208,"score_gpt":0.1997205832521017,"score_spread":0.1840314887035096,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}