{"id":"W2162383397","doi":"10.1002/anie.201303968","title":"H<sub>2</sub> Cleavage, Hydride Formation, and Catalytic Hydrogenation of Imines with Zinc Complexes of C<sub>5</sub>Me<sub>5</sub> and N‐Heterocyclic Carbenes","year":2013,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":102,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Hydride; Catalysis; Chemistry; Monomer; Cleavage (geology); Zinc; Catalytic hydrogenation; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Hydrogen; Materials science; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001791244,0.000390352,0.0004678172,0.000474101,0.0001413933,0.00009430033,0.0002597787,0.0002233534,0.0000367131],"category_scores_gemma":[0.0001919097,0.0003776277,0.0001462128,0.0004259889,0.000299661,0.001401518,0.0001316844,0.0001962246,0.00001742082],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001730203,"about_ca_system_score_gemma":0.0000424261,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009839218,"about_ca_topic_score_gemma":0.0001031586,"domain_scores_codex":[0.9974568,0.00002518524,0.0008574314,0.0005059437,0.0008526711,0.0003019298],"domain_scores_gemma":[0.9977311,0.0002101462,0.0008213427,0.0003133305,0.0007466091,0.0001774819],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006291161,0.0001447037,0.001229385,0.0002931239,0.000267701,0.000003264875,0.0003340657,0.00004573782,0.9877224,0.00009912563,0.001282972,0.008514609],"study_design_scores_gemma":[0.001318284,0.0000550365,0.002364695,0.0001985267,0.0001821922,0.00008798611,0.0003681114,0.001919112,0.9924616,0.0004993977,0.0001678706,0.0003772034],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960359,0.0003127239,0.00115645,0.0003964848,0.0001351633,0.0002365783,0.0002777642,0.00008094078,0.001368003],"genre_scores_gemma":[0.9959819,0.000715993,0.00006984954,0.0001247832,0.0003759522,0.0001266094,0.002536879,0.00004901596,0.00001896673],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008137406,"threshold_uncertainty_score":0.9998676,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008412366596511416,"score_gpt":0.2124520742492126,"score_spread":0.2040397076527012,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}