{"id":"W2162493990","doi":"10.1039/c3dt51846a","title":"Tuning ligand electronics and peripheral substitution on cobalt salen complexes: structure and polymerisation activity","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; University of Edinburgh; Compute Canada","keywords":"Chemistry; Reactivity (psychology); Ligand (biochemistry); Cobalt; Polymer chemistry; Cyclic voltammetry; Photochemistry; Polymerization; Styrene; Polymer; Copolymer; Organic chemistry; Electrochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001171502,0.0002207438,0.0001930854,0.0001138124,0.00007558175,0.000268327,0.0002691218,0.0001890138,0.0009190587],"category_scores_gemma":[0.000196305,0.00008357075,0.00009246855,0.0001488945,0.0001986685,0.0001692934,0.0001584924,0.0001885789,0.0002355734],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003241712,"about_ca_system_score_gemma":0.0001109244,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000374107,"about_ca_topic_score_gemma":0.0009994812,"domain_scores_codex":[0.9999161,0.00001332884,0.000006377136,0.00002051599,0.00002554937,0.0000182918],"domain_scores_gemma":[0.9999193,0.00001840862,0.00002319273,0.00001079155,0.00001515227,0.0000131542],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001284713,0.00001232068,0.0001078547,0.00005840931,0.000003499529,0.00002639678,0.00001747383,0.0002952182,0.9971405,0.00009056452,0.00002006048,0.002099233],"study_design_scores_gemma":[0.000009501151,0.0001686069,0.0004314626,0.000002505863,0.000006858999,0.00005725427,0.000007052176,0.0006495596,0.9978593,0.00001252437,0.000792452,0.00000288812],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961921,0.0005023673,0.001313268,0.00002716407,0.000004749127,0.00001598492,0.00005696651,0.00004049822,0.00184688],"genre_scores_gemma":[0.9977696,0.0002882943,0.0009521345,0.00001033477,0.000002435331,0.000007838572,0.00007177019,0.00001505529,0.0008827224],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009190587,"threshold_uncertainty_score":0.003074527,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01010530123448125,"score_gpt":0.2154537716104504,"score_spread":0.2053484703759691,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}