{"id":"W2162571092","doi":"10.1002/chin.200445278","title":"N‐Heterocyclic Carbenes: Exotic Molecules as Precursors to Unusual Hydrogen Bonds","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Hydrogen bond; Molecule; Computational chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001212169,0.0001765801,0.0001267498,0.0001603105,0.000280402,0.000605481,0.0003496075,0.0003415611,0.00584306],"category_scores_gemma":[0.0002091089,0.0001319462,0.0000889207,0.0001852395,0.0003533001,0.0009914605,0.0003994798,0.0006164934,0.0007382372],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002771491,"about_ca_system_score_gemma":0.0001354585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003422651,"about_ca_topic_score_gemma":0.0009242275,"domain_scores_codex":[0.9999366,0.00001013475,0.00000191743,0.00001844166,0.00001883712,0.00001408329],"domain_scores_gemma":[0.9999338,0.00002047466,0.000007508233,0.00001477315,0.000008335415,0.00001506036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000388662,0.0001471127,0.0008433122,0.0007266908,0.00003840652,0.0009580255,0.0003355254,0.002627368,0.685958,0.2397548,0.00953015,0.05869189],"study_design_scores_gemma":[0.0001607719,0.001029692,0.003061301,0.00008016957,0.00005182657,0.002036816,0.0003141689,0.007587455,0.6976197,0.04356633,0.2443951,0.00009670093],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6710572,0.0197219,0.02923195,0.001290976,0.0007791535,0.0001162927,0.0008759269,0.0004819319,0.2764447],"genre_scores_gemma":[0.981425,0.003919947,0.004095526,0.0001669444,0.00005468321,0.00002983396,0.0002196779,0.00003329171,0.01005506],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00584306,"threshold_uncertainty_score":0.01954705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.010664006951768,"score_gpt":0.233793221364359,"score_spread":0.223129214412591,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}