{"id":"W2162683372","doi":"10.1002/chem.201402875","title":"Zincocene and Dizincocene N‐Heterocyclic Carbene Complexes and Catalytic Hydrogenation of Imines and Ketones","year":2014,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Alexander von Humboldt-Stiftung","keywords":"Carbene; IMes; Adduct; Chemistry; Catalysis; Medicinal chemistry; Benzophenone; Ligand (biochemistry); Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003729227,0.0002162519,0.0003057815,0.00007412014,0.0001814855,0.00008962474,0.0001595289,0.00005073565,0.0001180376],"category_scores_gemma":[0.0002541767,0.0002001286,0.00006150159,0.0001365455,0.0002157753,0.0001471497,0.0001410979,0.0001987834,0.000002176654],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002046128,"about_ca_system_score_gemma":0.00001261609,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005528395,"about_ca_topic_score_gemma":6.778645e-7,"domain_scores_codex":[0.9987804,0.00005017971,0.0004508682,0.000285933,0.0002330051,0.0001996317],"domain_scores_gemma":[0.9989845,0.00009885206,0.0003426576,0.0002032397,0.0001004192,0.0002703459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000340384,0.00006839277,0.006224965,0.0005026308,0.0001503417,0.00003791781,0.0002516985,0.00001204598,0.9351319,0.00002249538,0.00007117895,0.05749242],"study_design_scores_gemma":[0.002152592,0.00003819351,0.008386941,0.0002029022,0.0002932708,0.002868494,0.0003575145,0.007367494,0.9726713,0.0001187845,0.00502225,0.0005202392],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901124,0.001503684,0.0001293158,0.0001317566,0.00001757697,0.0000196866,0.00001804246,0.00002758688,0.008039915],"genre_scores_gemma":[0.9986777,0.0004665619,0.0001838971,0.00003535329,0.0002048706,0.000001354137,0.00003149359,0.00003348082,0.0003652763],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05697218,"threshold_uncertainty_score":0.8161008,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008346275185818718,"score_gpt":0.2043985699401191,"score_spread":0.1960522947543004,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}