{"id":"W2162773724","doi":"10.1002/chin.200051109","title":"ChemInform Abstract: Amination of Bis(trimethylsilyl)‐1,2‐bisketene with Secondary Amines: Formation of Aminodihydrofuranones.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Organic Chemistry Synthesis Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Amination; Trimethylsilyl; Service (business); Combinatorial chemistry; Organic chemistry; Business; Marketing; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003250953,0.0004540512,0.0007042445,0.0001236518,0.00006772059,0.0000268465,0.0005470464,0.0004045693,0.02226778],"category_scores_gemma":[0.0002192929,0.0004152535,0.0002075722,0.0004531327,0.0002975507,0.0008457405,0.0000601869,0.0003389643,0.00003049695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002043945,"about_ca_system_score_gemma":0.0001606675,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000383658,"about_ca_topic_score_gemma":0.00000401349,"domain_scores_codex":[0.9972515,2.831875e-7,0.001293597,0.0003373517,0.0006698311,0.0004474946],"domain_scores_gemma":[0.997436,0.0003136441,0.0009274111,0.0008661447,0.0002977639,0.0001590556],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001238844,0.00008672113,0.00002583752,0.001387834,0.00004452801,0.000001997718,0.0005888462,7.693553e-7,0.4873137,0.000005825655,0.0004614488,0.5099586],"study_design_scores_gemma":[0.001331795,0.00004049288,0.0004893991,0.0003011861,0.00009989933,0.00006752157,0.0008901567,0.00004568278,0.9828083,0.00002313807,0.01345891,0.0004435405],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3339879,0.0001793586,0.000003577549,0.00002143376,0.00002296944,0.0001148883,0.00008284568,0.00009042042,0.6654966],"genre_scores_gemma":[0.9656358,0.0001358272,0.0006715088,0.00001955257,0.0001061367,0.00003165297,0.0003202141,0.00005852745,0.03302078],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6324759,"threshold_uncertainty_score":0.9998299,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0110516821069373,"score_gpt":0.2346560019486204,"score_spread":0.2236043198416831,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}