{"id":"W2162890179","doi":"10.1021/jp0200831","title":"Microwave Spectrum, Geometry, and Hyperfine Constants of PdCO","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hyperfine structure; Isotopomers; Rotational spectroscopy; Quadrupole; Atomic physics; Chemistry; Microwave; Molecular geometry; Coupling constant; Rotational transition; Spectral line; Nuclear magnetic resonance; Molecule; Molecular physics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008552695,0.0001452932,0.0003109315,0.0000130586,0.00004766417,0.00001272534,0.00026521,0.0000677823,0.001048057],"category_scores_gemma":[0.00006740892,0.00009591992,0.0001280692,0.0001067589,0.0002322549,0.00003814313,0.00005211081,0.0004539248,0.000002274305],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002208708,"about_ca_system_score_gemma":0.00001603363,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002140828,"about_ca_topic_score_gemma":2.722656e-7,"domain_scores_codex":[0.9991956,0.00001432474,0.0002683099,0.00009233712,0.000257601,0.0001718402],"domain_scores_gemma":[0.9992032,0.0001056691,0.00031407,0.000225645,0.00005582768,0.00009559998],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007187673,0.00008977574,0.00004668536,0.0001152462,0.00008499922,0.00002400003,0.000220123,0.00002915706,0.9986374,0.00008492992,0.0002483389,0.0003474749],"study_design_scores_gemma":[0.0005282082,0.00004719902,0.00004344642,0.00006412657,0.00009805707,0.0005376436,0.00009371267,0.0005850677,0.9960642,0.001477295,0.0003636013,0.00009745457],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9806034,0.0009392343,0.00007917892,0.0002257146,0.000009875524,0.00001463078,0.00001392632,0.000005128931,0.01810894],"genre_scores_gemma":[0.9990613,0.00009755893,0.00005673857,0.00002792066,0.0003563707,2.006837e-7,7.310689e-7,0.00001159536,0.0003875488],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01845797,"threshold_uncertainty_score":0.9998651,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00691132009315922,"score_gpt":0.214974578046685,"score_spread":0.2080632579535258,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}