{"id":"W2162890179","doi":"10.1021/jp0200831","title":"Microwave Spectrum, Geometry, and Hyperfine Constants of PdCO","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hyperfine structure; Isotopomers; Rotational spectroscopy; Quadrupole; Atomic physics; Chemistry; Microwave; Molecular geometry; Coupling constant; Rotational transition; Spectral line; Nuclear magnetic resonance; Molecule; Molecular physics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001043959,0.0001607379,0.0001386899,0.0005501945,0.000280099,0.0001480456,0.0002133026,0.0001460439,0.001570229],"category_scores_gemma":[0.0003286263,0.00008760344,0.00004363522,0.0004734308,0.0002371202,0.0001873151,0.0001392908,0.0002581541,0.0001704842],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002956503,"about_ca_system_score_gemma":0.0001167111,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001220312,"about_ca_topic_score_gemma":0.00110139,"domain_scores_codex":[0.9999306,0.000006024126,0.000001653753,0.0000190289,0.00002734674,0.00001538922],"domain_scores_gemma":[0.9998259,0.00003885437,0.00003812387,0.0000217731,0.00005192679,0.0000234261],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001722827,0.00002521924,0.002889971,0.00004985078,0.00000736332,0.0000921632,0.0001058294,0.0003956731,0.9872707,0.001062243,0.0002750199,0.00765367],"study_design_scores_gemma":[0.00003912709,0.0003479941,0.0772526,0.00001570125,0.000023324,0.0009089581,0.0001701051,0.003952156,0.909472,0.00084213,0.00694352,0.00003245795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926552,0.0003991102,0.00275889,0.00006739006,0.00000594148,0.000007396323,0.0003765677,0.00005460204,0.003674998],"genre_scores_gemma":[0.9974356,0.0002027738,0.00105784,0.00001778352,0.000004782615,0.000007567618,0.0003441311,0.0000134803,0.0009160889],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001570229,"threshold_uncertainty_score":0.005252898,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00691132009315922,"score_gpt":0.214974578046685,"score_spread":0.2080632579535258,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}