{"id":"W2163054865","doi":"10.1021/jp002676m","title":"A Study of Silver (I) Ion−Organonitrile Complexes:  Ion Structures, Binding Energies, and Substituent Effects","year":2001,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":74,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ion; Dissociation (chemistry); Substituent; Density functional theory; Acetonitrile; Enthalpy; Molecule; Binding energy; Crystallography; Standard enthalpy of formation; Bond-dissociation energy; Physical chemistry; Computational chemistry; Stereochemistry; Organic chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002601324,0.0006015222,0.0005802014,0.0001965316,0.0003835226,0.0004091521,0.0007169125,0.0004312792,0.002496085],"category_scores_gemma":[0.0003744806,0.0002802364,0.0002849406,0.0002639556,0.0002748173,0.0002746693,0.0002814576,0.0003594403,0.0004072886],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005162548,"about_ca_system_score_gemma":0.0002034929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002412662,"about_ca_topic_score_gemma":0.002595976,"domain_scores_codex":[0.9998348,0.00002960307,0.000006639061,0.00002988126,0.00006667268,0.00003238909],"domain_scores_gemma":[0.9998705,0.00004981407,0.00002550434,0.000009733028,0.00002749069,0.00001683767],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005520316,0.0002132706,0.001931356,0.0008733809,0.00006843099,0.0004820848,0.0002805127,0.0489114,0.9332417,0.003451761,0.0006474762,0.009346657],"study_design_scores_gemma":[0.0001446043,0.002154094,0.007978561,0.00008199297,0.0001689377,0.0006389527,0.0002680412,0.1631623,0.8177012,0.001238074,0.00638585,0.00007736789],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906071,0.001041061,0.002899174,0.00005945719,0.00001409138,0.00002135362,0.0001158581,0.00007223443,0.005169557],"genre_scores_gemma":[0.994844,0.0006117944,0.002261814,0.00002555706,0.000004325181,0.0000249272,0.0002274635,0.00004016972,0.001960068],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002496085,"threshold_uncertainty_score":0.008350253,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009989347154129778,"score_gpt":0.2540984843413802,"score_spread":0.2441091371872504,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}