{"id":"W2163393145","doi":"10.1351/pac-con-13-03-04","title":"[Ru(bpy)3]2+* and other remarkable metal-to-ligand charge transfer (MLCT) excited states","year":2013,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":311,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Excited state; Chemistry; Photochemistry; Electron transfer; Quenching (fluorescence); Dication; Ultrafast laser spectroscopy; Chemical physics; Femtosecond; Molecule; Atomic physics; Spectroscopy; Fluorescence; Laser; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008388531,0.0004504937,0.000465136,0.00001882302,0.0002254591,0.0001182093,0.0001975852,0.0002465568,0.002021904],"category_scores_gemma":[0.000009375325,0.0004123334,0.00007099458,0.0001339631,0.0001525895,0.0000765943,0.00006099921,0.0003507511,0.0000412609],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002399411,"about_ca_system_score_gemma":0.00002410301,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003339443,"about_ca_topic_score_gemma":0.000003001907,"domain_scores_codex":[0.9981482,0.000003936789,0.0003160311,0.0006783454,0.0002127825,0.0006406959],"domain_scores_gemma":[0.9992003,0.00005575994,0.00003027409,0.0003397616,0.00004365729,0.0003301844],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000070756,0.00007283631,0.0002435781,0.000715243,0.0001801242,0.000002563853,0.0004673747,0.000001426311,0.9951547,0.00007935494,0.001939555,0.001072525],"study_design_scores_gemma":[0.0008640539,0.00001050023,0.00003268421,0.00005024982,0.00008256157,0.00002303636,0.0003905408,0.00003760972,0.9669155,0.0009030113,0.03018727,0.0005029351],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.921676,0.0009593574,0.0000840217,0.0003600081,0.00001106822,0.0002063328,0.00009324838,0.0001401843,0.07646973],"genre_scores_gemma":[0.9924045,0.000350954,0.00005389989,0.0005119167,0.0001749409,0.0004407579,0.00006320747,0.0000562901,0.00594353],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07072845,"threshold_uncertainty_score":0.9998329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00662975733350549,"score_gpt":0.1967151228769701,"score_spread":0.1900853655434646,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}