{"id":"W2163440122","doi":"10.1139/cjc-2015-0174","title":"Synthesis and conformational studies of 9-benzyloxy-18-substituted [3.3]metacyclophanes","year":2015,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Demethylation; Intramolecular force; Ring (chemistry); Solid-state; Stereochemistry; Nucleophile; Proton NMR; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003100872,0.00013285,0.0003739303,0.00005535069,0.00006377967,0.00003835918,0.0002382608,0.00008151541,0.0007478393],"category_scores_gemma":[0.00138545,0.0001116929,0.00008181891,0.00005840159,0.0002677707,0.0001619381,0.00001981588,0.0001229503,0.000002458809],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009859104,"about_ca_system_score_gemma":0.001020546,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002597924,"about_ca_topic_score_gemma":0.0001156935,"domain_scores_codex":[0.9989884,0.00001028202,0.0005144615,0.00007912789,0.0002342039,0.0001735177],"domain_scores_gemma":[0.9982958,0.0002138049,0.0003577684,0.0001564587,0.0004701377,0.0005060397],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005456093,0.0001890896,0.04002754,0.00597295,0.004882831,0.0006423516,0.0194773,0.0003962896,0.7862934,0.0003235248,0.08164619,0.05960289],"study_design_scores_gemma":[0.0007044767,0.00001812875,0.0003939269,0.0007096333,0.0001364478,0.0006662167,0.008781847,0.00005961007,0.9621694,0.001024826,0.02505264,0.0002828173],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9686077,0.007345086,0.000002795844,0.0003266573,0.0000871891,0.00001339198,0.00002438252,0.000004607172,0.02358821],"genre_scores_gemma":[0.9990091,0.0001169985,0.0003660704,0.00002166677,0.000150067,0.000001973974,0.00000216495,0.00001000775,0.0003219985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.175876,"threshold_uncertainty_score":0.8188316,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06137697868738814,"score_gpt":0.2514540925209384,"score_spread":0.1900771138335502,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}