{"id":"W2164107679","doi":"10.1039/b513374m","title":"Asymmetric allylic oxidation reactions catalyzed by a chiral nonracemic and C<sub>2</sub>-symmetric 2,2′-bipyridyl copper(<scp>i</scp>) complex","year":2005,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Allylic rearrangement; Chemistry; Copper; Catalysis; Ligand (biochemistry); Enantioselective synthesis; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002772624,0.0009527277,0.0007252725,0.0002415244,0.0005202359,0.0002554194,0.0007329218,0.0007832538,0.0009969028],"category_scores_gemma":[0.001620414,0.001135608,0.0002960538,0.002523508,0.000367871,0.0003265462,0.0003969755,0.001014486,0.0004348084],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00102257,"about_ca_system_score_gemma":0.0003088469,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003524423,"about_ca_topic_score_gemma":0.000008011506,"domain_scores_codex":[0.9954144,0.00004697192,0.001010682,0.001572455,0.0008455763,0.001109885],"domain_scores_gemma":[0.996519,0.0004104473,0.0006754332,0.001380581,0.0002842916,0.0007303015],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001412759,0.0005116525,0.0001197056,0.0003505946,0.0002868557,0.00002738044,0.0000820756,7.585057e-7,0.9853143,0.000007734967,0.01085896,0.002425873],"study_design_scores_gemma":[0.00177687,0.00001748964,0.000143306,0.00007020022,0.0002704348,0.0007210333,0.0003513355,0.0004591017,0.9590575,0.00002486417,0.0365296,0.0005782998],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9673634,0.002262387,0.003916713,0.0005724232,0.00007858939,0.0002616695,0.0003581117,0.0006553164,0.02453145],"genre_scores_gemma":[0.9925805,0.0007082368,0.0004658293,0.0001615573,0.0004904805,0.00007071136,0.002478199,0.0002490711,0.00279538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02625682,"threshold_uncertainty_score":0.9999163,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008370511141705457,"score_gpt":0.220372447127672,"score_spread":0.2120019359859666,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}