{"id":"W2164173549","doi":"10.1016/j.ssnmr.2015.10.005","title":"Minimizing the effects of RF inhomogeneity and phase transients allows resolution of two peaks in the 1H CRAMPS NMR spectrum of adamantane","year":2015,"lang":"en","type":"article","venue":"Solid State Nuclear Magnetic Resonance","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"Redeemer University","funders":"","keywords":"Homonuclear molecule; Adamantane; Decoupling (probability); Phase (matter); Limiting; Chemistry; Solid-state nuclear magnetic resonance; Nuclear magnetic resonance; Spectral line; NMR spectra database; Analytical Chemistry (journal); Materials science; Molecule; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000683661,0.0007730541,0.0005822698,0.0002248291,0.0004170724,0.0004974123,0.0004078879,0.0004301748,0.002356289],"category_scores_gemma":[0.001055816,0.0003555271,0.0001753489,0.0003897077,0.0005228422,0.0006243138,0.0004757056,0.0008398576,0.000544604],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001911688,"about_ca_system_score_gemma":0.0005728804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004677108,"about_ca_topic_score_gemma":0.001446817,"domain_scores_codex":[0.999731,0.00005177136,0.00001829544,0.0000795442,0.0000800347,0.00003924317],"domain_scores_gemma":[0.9994612,0.0002291803,0.00008368628,0.0001126643,0.00006135583,0.00005190167],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007669617,0.00001972392,0.0001363627,0.00004451866,0.000004481276,0.00002645198,0.00002855854,0.000215338,0.9925518,0.0001428589,0.00005687521,0.006696338],"study_design_scores_gemma":[0.00001305857,0.0001240535,0.001523552,0.000004719473,0.00001077799,0.0001938194,0.00002178881,0.001358376,0.9950964,0.0001649999,0.001476253,0.0000121739],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8460221,0.0009153713,0.146963,0.0004581593,0.00007458716,0.00008011419,0.0002771897,0.001146036,0.004063299],"genre_scores_gemma":[0.8747538,0.001093761,0.1198774,0.0001559517,0.00004125086,0.0001066198,0.0003582822,0.0008402389,0.002772704],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.002356289,"threshold_uncertainty_score":0.007882595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01450347984310862,"score_gpt":0.2884619903112206,"score_spread":0.273958510468112,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}