{"id":"W2164222656","doi":"10.1002/anie.201207610","title":"A Luminescent Metal–Organic Framework as a Turn‐On Sensor for DMF Vapor","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":375,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Luminescence; Turn (biochemistry); Lanthanide; Metal-organic framework; Metal; Ligand (biochemistry); Coordination sphere; Dimethylformamide; Chemistry; Photochemistry; Water vapor; Inorganic chemistry; Materials science; Physical chemistry; Organic chemistry; Optoelectronics; Ion; Receptor; Solvent; Adsorption","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002212535,0.0002716461,0.0002440031,0.00007706577,0.0001365454,0.0000745072,0.0003248667,0.0003208515,0.01106273],"category_scores_gemma":[0.001071005,0.000256299,0.0002425681,0.0001391224,0.00005457842,0.0002394926,0.00005644302,0.0003290865,0.000430289],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002129033,"about_ca_system_score_gemma":0.00003681156,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008488157,"about_ca_topic_score_gemma":0.00000125638,"domain_scores_codex":[0.9983569,0.00001042519,0.0003898297,0.0003846388,0.000478026,0.0003801688],"domain_scores_gemma":[0.9984555,0.000483654,0.0002538275,0.0004002712,0.0002150675,0.00019165],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001440889,0.0008713583,0.0002766319,0.00009080727,0.0003331593,0.00000250626,0.0003222138,0.000002628675,0.9516579,0.01586672,0.02789848,0.002533524],"study_design_scores_gemma":[0.000332454,0.00001653655,0.0001199896,0.0001471101,0.00008951889,0.00002499068,0.0001829969,0.00003456141,0.8584834,0.003695452,0.1366196,0.0002533885],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7037902,0.001410535,0.1352146,0.02533613,0.01131791,0.001597825,0.002144529,0.001116987,0.1180713],"genre_scores_gemma":[0.9827631,0.00009981614,0.003160925,0.001012995,0.00798613,0.0004587535,0.0007841976,0.00006759149,0.003666499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2789729,"threshold_uncertainty_score":0.9999889,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02140010363623923,"score_gpt":0.2792282645469927,"score_spread":0.2578281609107535,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}