{"id":"W2164510736","doi":"10.1002/anie.200802713","title":"Metal Complexes of Aminyl Radicals","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Radical; Metal; Amide; Valence (chemistry); Chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007299092,0.0001272859,0.0002252136,0.00008009939,0.00006436477,0.00001131942,0.0002754738,0.00006861238,0.05016758],"category_scores_gemma":[0.0001132633,0.0001234066,0.0001990004,0.00009087299,0.0001668542,0.0001639007,0.00006224492,0.0000872474,0.00004775874],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006132999,"about_ca_system_score_gemma":0.00002618071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004445343,"about_ca_topic_score_gemma":0.000003506321,"domain_scores_codex":[0.99887,0.000005870491,0.0003292944,0.0002151103,0.0004530497,0.0001267433],"domain_scores_gemma":[0.9993335,0.0001000241,0.0001771891,0.0001977531,0.0001307982,0.00006076006],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002231947,0.0001857849,0.0005853375,0.00002685859,0.0002154999,0.000009528913,0.0001074688,0.000002099566,0.9928495,0.0005455148,0.003781428,0.00166862],"study_design_scores_gemma":[0.0002772934,0.00000716607,0.001348708,0.0000227105,0.00003952976,0.00004539554,0.00005869423,0.00002946031,0.9335713,0.0003813412,0.06409919,0.0001191443],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.849419,0.000297552,0.001229866,0.0005810151,0.0004026399,0.00004020047,0.0003892952,0.00009273456,0.1475477],"genre_scores_gemma":[0.9939354,0.0001395279,0.0002595611,0.00005385374,0.0009090836,0.00001580428,0.0007020906,0.00001520504,0.003969489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1445164,"threshold_uncertainty_score":0.9507007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02462433386765453,"score_gpt":0.2464938200774789,"score_spread":0.2218694862098243,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}