{"id":"W2164735723","doi":"10.1002/0471264180.os079.26","title":"Preparation of 1‐[N‐Benzyloxycarbonyl‐(1S)‐1‐Amino‐2‐Oxoethyl]‐4‐Methyl‐2,6,7‐Trioxabicyclo[2.2.2]Octane","year":2003,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Hemoglobin structure and function","field":"Biochemistry, Genetics and Molecular Biology","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Octane; Chemistry; Oxetane; Bicyclic molecule; Amino acid; Hydroxymethyl; Medicinal chemistry; Stereochemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001740149,0.0004446895,0.0005121985,0.0001625016,0.00004409955,0.00002184422,0.000287065,0.0009323407,0.002965792],"category_scores_gemma":[0.0005985188,0.0004151611,0.0001882363,0.0002025947,0.0001374611,0.000003785701,0.00008325066,0.0001612421,0.00005997266],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003203864,"about_ca_system_score_gemma":0.0001925197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008685794,"about_ca_topic_score_gemma":0.0001773431,"domain_scores_codex":[0.9981876,0.0001487579,0.0004004129,0.0006541366,0.0002819441,0.0003271454],"domain_scores_gemma":[0.99849,0.00004568774,0.0004039561,0.0008802683,0.00008274984,0.00009727744],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00006364408,0.00007486432,0.0001820836,0.0001354972,0.0002878332,0.000003876303,0.00003594002,0.000001525046,0.6867877,0.00007469882,0.3084877,0.003864671],"study_design_scores_gemma":[0.0001670245,0.000191089,0.00003903607,0.00009268108,0.000100002,0.00002631956,0.00003481849,0.000001267205,0.3664331,0.00003629008,0.6325445,0.000333951],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.01435745,0.01042304,0.001852201,0.00008404784,0.00264414,0.0009493119,0.0002916045,0.0001608767,0.9692373],"genre_scores_gemma":[0.3733322,0.0018211,0.001353301,0.0002133284,0.001474183,0.00004322549,0.0004143392,0.0007689936,0.6205793],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.3589748,"threshold_uncertainty_score":0.99983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008011451401414052,"score_gpt":0.2538989648717933,"score_spread":0.2458875134703793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}