{"id":"W2164735723","doi":"10.1002/0471264180.os079.26","title":"Preparation of 1‐[N‐Benzyloxycarbonyl‐(1S)‐1‐Amino‐2‐Oxoethyl]‐4‐Methyl‐2,6,7‐Trioxabicyclo[2.2.2]Octane","year":2003,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Hemoglobin structure and function","field":"Biochemistry, Genetics and Molecular Biology","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Octane; Chemistry; Oxetane; Bicyclic molecule; Amino acid; Hydroxymethyl; Medicinal chemistry; Stereochemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001116078,0.0003486937,0.0001607955,0.0002211394,0.0001751133,0.0001528195,0.0002357986,0.0001468893,0.002919158],"category_scores_gemma":[0.0001066815,0.0001618844,0.00009149042,0.0001480886,0.00009608261,0.0001618606,0.0001994269,0.0003683903,0.00160996],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002168006,"about_ca_system_score_gemma":0.0003972775,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005511792,"about_ca_topic_score_gemma":0.001332666,"domain_scores_codex":[0.9999247,0.000008145294,0.000004253686,0.00001312794,0.0000262974,0.00002347077],"domain_scores_gemma":[0.9999349,0.000008475655,0.00001275828,0.000008387415,0.0000137767,0.00002163777],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000351236,0.00001761663,0.00003252256,0.00003757942,0.000001867767,0.00003589045,0.00001040222,0.0001156772,0.9963698,0.0001746327,0.0001042113,0.003064579],"study_design_scores_gemma":[0.00002545427,0.0001144815,0.0005386256,0.000006006878,0.00000389565,0.00007657651,0.0000115435,0.0003174105,0.9872819,0.00004540718,0.01157401,0.00000477305],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.900017,0.003719829,0.06375495,0.0003214097,0.0003168831,0.0005659214,0.002162261,0.0004539044,0.02868775],"genre_scores_gemma":[0.897787,0.004741316,0.03166825,0.0002030776,0.00005425773,0.0003646382,0.003583997,0.000224011,0.06137332],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002919158,"threshold_uncertainty_score":0.009765565,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008011451401414052,"score_gpt":0.2538989648717933,"score_spread":0.2458875134703793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}