{"id":"W2164843572","doi":"10.1002/chin.200827170","title":"ChemInform Abstract: An Efficient Three‐Component One‐Pot Approach to the Synthesis of 2,3,4,5‐Tetrahydro‐1H‐2‐benzazepines by Means of Rhodium‐Catalyzed Hydroaminomethylation.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Benzazepines; Chemistry; Rhodium; Component (thermodynamics); Catalysis; Service (business); Combinatorial chemistry; Stereochemistry; Organic chemistry; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003019117,0.001132407,0.0006031771,0.0005367678,0.0003680165,0.0004874789,0.001172821,0.0005062927,0.01019972],"category_scores_gemma":[0.0002005864,0.0005126909,0.0004727197,0.0003629471,0.0002998687,0.0007237946,0.0006933365,0.001076236,0.008373268],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004566632,"about_ca_system_score_gemma":0.001056349,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007597329,"about_ca_topic_score_gemma":0.001753157,"domain_scores_codex":[0.999792,0.00003090165,0.00001684791,0.00005219458,0.00006206855,0.00004593359],"domain_scores_gemma":[0.9999323,0.00001002469,0.00001340404,0.00001387589,0.00001064884,0.00001981929],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004456519,0.0002253097,0.0001275604,0.001765193,0.00009560506,0.0006265779,0.0002090861,0.001504382,0.8936872,0.00445568,0.0134438,0.08341404],"study_design_scores_gemma":[0.0002008423,0.0008088981,0.0007391481,0.0000468385,0.00007977396,0.0008555841,0.00002811584,0.00232141,0.9333196,0.0007582535,0.06076092,0.0000805297],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.408466,0.02710231,0.3325355,0.0023972,0.002617173,0.002867372,0.01337704,0.01694118,0.1936963],"genre_scores_gemma":[0.7996404,0.01581761,0.08138304,0.000635434,0.0002923009,0.000462659,0.006722629,0.001103438,0.09394252],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01019972,"threshold_uncertainty_score":0.03412145,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02441922800082543,"score_gpt":0.2208844135189174,"score_spread":0.1964651855180919,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}