{"id":"W2165062754","doi":"10.1021/ar0682029","title":"Solvent Effects on the Rates and Mechanisms of Reaction of Phenols with Free Radicals","year":2007,"lang":"en","type":"article","venue":"Accounts of Chemical Research","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":632,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Chemistry; Radical; Hydrogen atom abstraction; Dissociation (chemistry); Hydrogen atom; Photochemistry; Solvation; Electron transfer; Proton; Proton-coupled electron transfer; Solvent; Computational chemistry; Ion; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001429741,0.0001088837,0.0002675854,0.00006600894,0.00003708556,0.00001033806,0.0004058084,0.0001442895,0.0001136276],"category_scores_gemma":[0.001342496,0.00006601318,0.00005022743,0.0001958009,0.0005400039,0.00005401445,0.000132438,0.0003691697,0.000002187227],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003210923,"about_ca_system_score_gemma":0.00005227444,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009869397,"about_ca_topic_score_gemma":0.000003618124,"domain_scores_codex":[0.9980398,0.00002925878,0.0003064874,0.0002127822,0.001090658,0.0003210143],"domain_scores_gemma":[0.996821,0.002269655,0.0001362497,0.0004547249,0.0002232567,0.00009504955],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003973426,0.0001946233,0.0002390285,0.0004115436,0.00004690053,0.000004518361,0.00003421019,7.321661e-8,0.9877875,0.007216843,0.0004628486,0.003204532],"study_design_scores_gemma":[0.0006360772,0.000131732,0.0005595262,0.0005197137,0.00001102311,0.000002913873,0.0001037169,0.00001611126,0.9859164,0.01191846,0.00012026,0.00006400938],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950795,0.0001468566,0.00006086263,0.0003995746,0.00001005702,0.0001222796,0.00001387846,0.000007387839,0.004159615],"genre_scores_gemma":[0.9995961,0.00006204996,0.0001745028,0.00002101274,0.00005537479,0.000008719356,0.000003046543,0.00001565551,0.00006350368],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004701615,"threshold_uncertainty_score":0.2691939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02922136919815126,"score_gpt":0.3251736095159953,"score_spread":0.295952240317844,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}