{"id":"W2165070003","doi":"10.1002/anie.201205943","title":"Catalytic Hydrogen/Deuterium Exchange of Unactivated Carbon–Hydrogen Bonds by a Pentanuclear Electron‐Deficient Nickel Hydride Cluster","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Catalysis; Deuterium; Cluster (spacecraft); Hydrogen; Nickel; Hydride; Chemistry; Benzene; Hydrogen–deuterium exchange; Transition metal; Carbon fibers; Inorganic chemistry; Crystallography; Polymer chemistry; Materials science; Organic chemistry; Physics; Atomic physics; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002045251,0.0002922197,0.0003324326,0.0001350437,0.00006654065,0.00003431914,0.0003926768,0.0001584248,0.006364475],"category_scores_gemma":[0.00006759821,0.0003002643,0.0002193735,0.00021071,0.00009095093,0.0003312959,0.0001688326,0.0001915233,0.00005471295],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004440706,"about_ca_system_score_gemma":0.00003308559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000216887,"about_ca_topic_score_gemma":0.000009932211,"domain_scores_codex":[0.9980047,0.00001677609,0.0004828802,0.0003815702,0.0006579375,0.0004561193],"domain_scores_gemma":[0.9988995,0.00007501639,0.0003370404,0.0003868244,0.0001360066,0.0001656507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006882323,0.0004313373,0.0004243015,0.00007293776,0.0003402981,0.000001817557,0.0003130941,0.000006351357,0.9930128,0.0000361459,0.004791168,0.0005008646],"study_design_scores_gemma":[0.0005014036,0.00002110542,0.00009812346,0.00004293012,0.0001441152,0.00003000687,0.0001101932,0.0002705427,0.9412574,0.00003522512,0.05720219,0.0002867307],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9505401,0.0007160281,0.00004909106,0.0004275931,0.0003010874,0.00009048705,0.0004281903,0.00008122915,0.04736614],"genre_scores_gemma":[0.9916378,0.0001025753,0.00001977921,0.0001388844,0.001272676,0.00005944376,0.002346783,0.00005709291,0.004364986],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05241103,"threshold_uncertainty_score":0.9999449,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01045049051746956,"score_gpt":0.2298623185179208,"score_spread":0.2194118280004512,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}