{"id":"W2165209739","doi":"10.1515/znb-2009-0909","title":"An Exploration of the Metal Oxide-assisted Decomposition and Rearrangement of N-Acyl-1,3-oxazolidin-2-ones Leading to 2-Aryl-2-oxazolines [1]","year":2009,"lang":"en","type":"article","venue":"Zeitschrift für Naturforschung B","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; Toronto Metropolitan University; Acadia University","funders":"Natural Sciences and Engineering Research Council of Canada; Acadia University","keywords":"Enantiopure drug; Oxazoline; Aryl; Chemistry; Ring (chemistry); Context (archaeology); Oxide; Metal; Alkyl; Medicinal chemistry; Decomposition; Product (mathematics); Combinatorial chemistry; Organic chemistry; Enantioselective synthesis; Mathematics; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003295277,0.0002580467,0.0004493965,0.0002864304,0.00009219912,0.00003435076,0.0003304949,0.0001709191,0.00002150122],"category_scores_gemma":[0.0002486633,0.0002183557,0.0001698362,0.0008748894,0.00005686516,0.0007023047,0.00008562562,0.0002173666,0.000005023303],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002260016,"about_ca_system_score_gemma":0.00002651128,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000418098,"about_ca_topic_score_gemma":0.0000293473,"domain_scores_codex":[0.9981281,0.0000494704,0.0006835479,0.0003803814,0.0004949925,0.0002634842],"domain_scores_gemma":[0.9986504,0.00009491602,0.0002728248,0.0005836441,0.0002613198,0.0001368555],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007927487,0.00009547216,0.0006881666,0.0000684351,0.00006438614,8.920047e-7,0.0004980929,0.008150467,0.9811739,0.006948338,0.00005918641,0.002173444],"study_design_scores_gemma":[0.0005410617,0.0001116852,0.01335061,0.0001840807,0.0001702601,0.000009076939,0.0002188382,0.01132039,0.9730225,0.0001309192,0.0006509564,0.0002896478],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905282,0.0003610144,0.007268808,0.0004747059,0.0001962922,0.0003911126,0.00003127081,0.0001205258,0.0006280574],"genre_scores_gemma":[0.9959727,0.00003804538,0.003585722,0.0001328627,0.00008086108,0.00001918202,0.00007165912,0.00003362859,0.000065369],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01266245,"threshold_uncertainty_score":0.8904288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02220059664225508,"score_gpt":0.3162539138152609,"score_spread":0.2940533171730058,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}