{"id":"W2165260099","doi":"10.1039/b211540a","title":"Surfactant assisted chemical vapour generation of silver for AAS and ICP-OES: a mechanistic study","year":2003,"lang":"en","type":"article","venue":"Journal of Analytical Atomic Spectrometry","topic":"nanoparticles nucleation surface interactions","field":"Earth and Planetary Sciences","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Chemistry; Analyte; Pulmonary surfactant; Diffusion; Analytical Chemistry (journal); Inductively coupled plasma atomic emission spectroscopy; Selenium; Chromatography; Inductively coupled plasma; Plasma; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006183108,0.0001124282,0.0003482446,0.0002232834,0.00005566885,0.00004986894,0.00009804696,0.00005284354,0.001191619],"category_scores_gemma":[0.0007150583,0.0000878614,0.0001234754,0.000370375,0.00006165043,0.0001818823,0.000005151105,0.0001639051,0.00001313946],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003230721,"about_ca_system_score_gemma":0.00008566603,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002992357,"about_ca_topic_score_gemma":0.00003971242,"domain_scores_codex":[0.9986088,0.00009275534,0.0006293664,0.0001549067,0.0003284747,0.0001857558],"domain_scores_gemma":[0.9987429,0.0004869625,0.0003071846,0.0001061639,0.0001926143,0.0001641795],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0009887981,0.001720775,0.3947597,0.00006868423,0.001297008,0.0001023317,0.0005750532,0.0009909169,0.5890403,0.004330649,0.002096808,0.004029037],"study_design_scores_gemma":[0.008235668,0.006400101,0.5393533,0.00009716743,0.001825672,0.001585605,0.00645244,0.2161443,0.2078201,0.009916411,0.001269203,0.0009000784],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969096,0.00009397251,0.002265468,0.0001675561,0.0001848613,0.0001436281,0.00002072629,0.000005885875,0.000208315],"genre_scores_gemma":[0.9937668,0.00001100508,0.006054907,0.00003200458,0.00007409516,2.560771e-7,0.000002639349,0.000004935658,0.00005338042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3812202,"threshold_uncertainty_score":0.9997214,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04101032232123782,"score_gpt":0.2810796702484403,"score_spread":0.2400693479272025,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}