{"id":"W2165554878","doi":"10.1002/anie.201106127","title":"Chiral Hypervalent Iodine Reagents in Asymmetric Reactions","year":2011,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":172,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Canadian Institutes of Health Research","keywords":"Hypervalent molecule; Enantioselective synthesis; Reagent; Iodine; Chemistry; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001137678,0.0001952461,0.0001550801,0.0001898131,0.00006470174,0.00002667341,0.000286686,0.0001558807,0.01038468],"category_scores_gemma":[0.0003141164,0.0002165066,0.0001065354,0.0003292378,0.00006273086,0.0002808378,0.00007774055,0.0003415808,0.0001889439],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005229564,"about_ca_system_score_gemma":0.00004451892,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001963886,"about_ca_topic_score_gemma":0.00002908127,"domain_scores_codex":[0.9986085,0.000007508192,0.0003995823,0.0003779605,0.0003711202,0.0002353252],"domain_scores_gemma":[0.999224,0.00006272786,0.0001896138,0.0002674163,0.0001546121,0.0001016209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008257452,0.0007518064,0.009165877,0.0000499403,0.0001117847,0.00003975082,0.0002624491,0.000002683249,0.981682,0.0003526472,0.006033366,0.001465131],"study_design_scores_gemma":[0.0007856369,0.000009546065,0.00652447,0.0000789504,0.00002224509,0.00005897477,0.0001924953,0.00004519819,0.9727775,0.0008074212,0.01848901,0.0002084934],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3454388,0.0000509331,0.0002757576,0.0004389653,0.001107952,0.00007631043,0.0002226137,0.0001791028,0.6522095],"genre_scores_gemma":[0.9896089,0.0001086624,0.0004245211,0.00006979365,0.001107646,0.00006610315,0.0007306228,0.00003004595,0.0078537],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6443558,"threshold_uncertainty_score":0.9905199,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04094357410536902,"score_gpt":0.2626180212418467,"score_spread":0.2216744471364777,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}