{"id":"W2165633163","doi":"10.1107/s1600536805029776","title":"Tris(2-<i>N</i>-methylaminocarbonyl-3-hydroxy-1,6-dimethyl-1,4-dihydro-4-pyridinonato)iron(III) dimethylformamide disolvate","year":2005,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Apotex (Canada)","funders":"","keywords":"Chemistry; Amide; Hydrogen bond; Denticity; Tris; Dimethylformamide; Crystal structure; Medicinal chemistry; Crystal (programming language); Crystallography; Stereochemistry; Molecule; Solvent; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001498483,0.0002518984,0.0001990011,0.00008977937,0.0001535775,0.000149744,0.000420936,0.000129104,0.004206528],"category_scores_gemma":[0.000126665,0.0001391496,0.00006168536,0.00009663909,0.0001327048,0.0001157666,0.0001732338,0.0002068768,0.001078703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002593016,"about_ca_system_score_gemma":0.0003404099,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009925427,"about_ca_topic_score_gemma":0.002995197,"domain_scores_codex":[0.9999082,0.000009333629,0.00000595807,0.00002690872,0.00002480409,0.0000247429],"domain_scores_gemma":[0.9999458,0.000008497104,0.00001575014,0.000005564991,0.000006518318,0.0000178403],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005416914,0.00004578376,0.0003269539,0.0002274286,0.00001091161,0.0001122199,0.00003240699,0.0002794794,0.9892482,0.0006017559,0.0007844197,0.007788771],"study_design_scores_gemma":[0.0001756746,0.0005825617,0.002042511,0.00001742618,0.00002055612,0.000325251,0.00003441019,0.0008697429,0.9639283,0.0001408466,0.03184799,0.00001475602],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9541727,0.00353388,0.01716434,0.0002889251,0.0003644379,0.0001804962,0.001205015,0.0009660403,0.02212419],"genre_scores_gemma":[0.9582498,0.001997088,0.01181233,0.0002067132,0.00005701521,0.0001697219,0.001305214,0.00006320694,0.02613894],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004206528,"threshold_uncertainty_score":0.0140723,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01309037055274778,"score_gpt":0.2508294521103152,"score_spread":0.2377390815575674,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}