{"id":"W2165928548","doi":"10.1103/physrevb.91.121114","title":"Hybridization effects and bond disproportionation in the bismuth perovskites","year":2015,"lang":"en","type":"article","venue":"Physical Review B","topic":"Magnetic and transport properties of perovskites and related materials","field":"Materials Science","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institute for Advanced Research","keywords":"Disproportionation; Bismuth; Ionic bonding; Atomic orbital; Octahedron; Orbital hybridisation; Crystallography; Perovskite (structure); Condensed matter physics; Materials science; Chemistry; Electron; Physics; Crystal structure; Ion; Quantum mechanics; Molecular orbital theory","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006200821,0.0001542113,0.0001279827,0.0001893879,0.0003569584,0.0002926541,0.0003403138,0.0002284119,0.001660566],"category_scores_gemma":[0.0001383097,0.0001399443,0.0001546687,0.00009383928,0.0004721021,0.0005146438,0.000347752,0.00024576,0.0001249609],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004590199,"about_ca_system_score_gemma":0.0001901109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005595389,"about_ca_topic_score_gemma":0.0009988325,"domain_scores_codex":[0.999957,0.000006850213,0.000002450148,0.000009236661,0.0000183888,0.00000605001],"domain_scores_gemma":[0.9999763,0.00000765044,0.000006997524,0.000003189105,0.00000271524,0.000003095494],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001420294,0.00006985715,0.0023454,0.000209603,0.00002607052,0.0007016335,0.0006766941,0.02265445,0.7233552,0.2338993,0.0003005495,0.01561927],"study_design_scores_gemma":[0.00009662686,0.0006090685,0.01420767,0.00004141124,0.000105767,0.002731222,0.00118483,0.1878906,0.6144767,0.1629717,0.01558897,0.00009549347],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762004,0.0007026001,0.01255588,0.0002655415,0.00001901786,0.00001756618,0.00002978447,0.0001019945,0.01010722],"genre_scores_gemma":[0.9956532,0.0002548213,0.002351971,0.00003116134,0.00000615845,0.00001883214,0.00001540669,0.00001477064,0.001653599],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001660566,"threshold_uncertainty_score":0.005555093,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01433246715159956,"score_gpt":0.2675938275876421,"score_spread":0.2532613604360425,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}