{"id":"W2166015787","doi":"10.1016/s0020-1693(02)01392-0","title":"X-ray crystal structure and ligand binding to β-tetrakis (trifluoromethyl)-meso-tetraphenylporphyrin cobalt(II)","year":2003,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Steric effects; Porphyrin; Tetraphenylporphyrin; Ligand (biochemistry); Trifluoromethyl; Cobalt; Crystallography; Binding constant; Pyridine; Crystal structure; Stereochemistry; Photochemistry; Inorganic chemistry; Medicinal chemistry; Binding site; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001032376,0.0001762302,0.0003363368,0.0001120065,0.0003941786,0.0004403982,0.0005787988,0.0003067954,0.001866443],"category_scores_gemma":[0.000206697,0.0001632958,0.0001155247,0.0002467207,0.0001793988,0.0001301005,0.00008407105,0.0006137927,0.0002387793],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001063122,"about_ca_system_score_gemma":0.0003029174,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01592911,"about_ca_topic_score_gemma":0.008270804,"domain_scores_codex":[0.9999139,0.000008206211,0.000004217706,0.00001804823,0.00003046774,0.00002511611],"domain_scores_gemma":[0.9999313,0.00002228619,0.00001360433,0.000004856093,0.0000127826,0.00001512089],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00190257,0.0004625818,0.006395384,0.0006014557,0.00008109707,0.000644193,0.0002088275,0.00695473,0.9647892,0.002783715,0.005357962,0.009818378],"study_design_scores_gemma":[0.0002842938,0.0002738834,0.03151032,0.00003718204,0.00005733843,0.0006010475,0.0002251849,0.01580281,0.9394394,0.0003452069,0.01139242,0.00003102356],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933839,0.0009419144,0.0006653353,0.0002265767,0.00001662747,0.000008604389,0.0008012665,0.00006506345,0.003890742],"genre_scores_gemma":[0.9933651,0.0006590122,0.0007628119,0.00007342244,0.000007521915,0.00001018969,0.002412044,0.0000214127,0.002688307],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01592911,"threshold_uncertainty_score":0.03167278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009918190585702945,"score_gpt":0.2289425388555647,"score_spread":0.2190243482698617,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}