{"id":"W2166015787","doi":"10.1016/s0020-1693(02)01392-0","title":"X-ray crystal structure and ligand binding to β-tetrakis (trifluoromethyl)-meso-tetraphenylporphyrin cobalt(II)","year":2003,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Steric effects; Porphyrin; Tetraphenylporphyrin; Ligand (biochemistry); Trifluoromethyl; Cobalt; Crystallography; Binding constant; Pyridine; Crystal structure; Stereochemistry; Photochemistry; Inorganic chemistry; Medicinal chemistry; Binding site; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003640864,0.0004824087,0.000520776,0.0001598565,0.0004407691,0.0002464772,0.0006382483,0.0002941804,0.002397232],"category_scores_gemma":[0.0004657538,0.0004522149,0.0000931879,0.0006685345,0.0001679933,0.000269267,0.0003016569,0.0004156767,0.00008782573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009649695,"about_ca_system_score_gemma":0.0001613373,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001879208,"about_ca_topic_score_gemma":0.000009462563,"domain_scores_codex":[0.9972079,0.00009559197,0.0005314688,0.0009095211,0.0004626022,0.0007929255],"domain_scores_gemma":[0.9982299,0.0001561187,0.000189339,0.0007304964,0.00008734169,0.0006068444],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002900819,0.00008248098,0.001530091,0.00005071633,0.00002402195,0.00001041473,0.0004748362,0.000001020631,0.9943892,0.0001962322,0.00319174,0.00002028359],"study_design_scores_gemma":[0.0006772248,0.0001407129,0.003804827,0.00004889253,0.00003731806,0.0002302475,0.00009815252,0.000002270054,0.9799506,0.0002721962,0.01417274,0.0005647835],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954475,0.0001148496,0.00001319196,0.0004219592,0.0005003955,0.000292741,0.0002988809,0.0001868004,0.002723749],"genre_scores_gemma":[0.9950818,0.00003049122,0.003682837,0.0003520549,0.0001825514,0.0000093324,0.00002680349,0.00007148186,0.0005626152],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01443852,"threshold_uncertainty_score":0.9997929,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009918190585702945,"score_gpt":0.2289425388555647,"score_spread":0.2190243482698617,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}