{"id":"W2166066662","doi":"10.1002/chem.200306019","title":"A Caged Lanthanide Complex as a Paramagnetic Shift Agent for Protein NMR","year":2004,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":101,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Lanthanide; Paramagnetism; Chemistry; Nuclear magnetic resonance spectroscopy; Molecule; Denticity; Diamagnetism; Crystallography; Spectroscopy; Metal; Nuclear magnetic resonance; Stereochemistry; Crystal structure; Magnetic field; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004717247,0.0004806162,0.0005947693,0.0002925151,0.0003405408,0.0005235356,0.0008975634,0.001001221,0.0007134897],"category_scores_gemma":[0.0005560693,0.0003111835,0.0002114684,0.000235519,0.0004943199,0.0006118608,0.0005378582,0.0008355845,0.0004884455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006655697,"about_ca_system_score_gemma":0.0003682091,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004244523,"about_ca_topic_score_gemma":0.0005359649,"domain_scores_codex":[0.9995214,0.0001070484,0.00002542975,0.0001325472,0.0001660135,0.00004765391],"domain_scores_gemma":[0.9996686,0.00007245121,0.00004593984,0.00005689451,0.00006689423,0.00008934209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003702421,0.000009794108,0.00003297678,0.00003391583,0.000003123103,0.00002066846,0.0000114189,0.00008743006,0.9983401,0.0002327994,0.00005094579,0.001139839],"study_design_scores_gemma":[0.00001915659,0.0001513544,0.0001729097,0.000003804947,0.000007401627,0.0002580537,0.000006534168,0.001715395,0.9941404,0.0000636495,0.003452105,0.000009161292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8554052,0.003543772,0.1359423,0.0006661739,0.0001591342,0.0003363231,0.0003520585,0.0008851137,0.002709939],"genre_scores_gemma":[0.8453465,0.001133841,0.1475765,0.0003032529,0.00004592746,0.0002328142,0.0009811993,0.0002012823,0.004178714],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001001221,"threshold_uncertainty_score":0.004829109,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03020314160751736,"score_gpt":0.2820372403639755,"score_spread":0.2518340987564581,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}