{"id":"W2166249123","doi":"10.1016/s0169-4332(02)00559-7","title":"Ce 3d XPS study of composite CexMn1−xO2−y wet oxidation catalysts","year":2002,"lang":"en","type":"article","venue":"Applied Surface Science","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":659,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Cerium; X-ray photoelectron spectroscopy; Catalysis; Valence (chemistry); Oxidation state; Stoichiometry; Manganese; Inorganic chemistry; Chemistry; Redox; Cerium nitrate; Materials science; Analytical Chemistry (journal); Chemical engineering; Physical chemistry; Environmental chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.002679535,0.0003056861,0.0004581863,0.0001919734,0.000618462,0.0003521846,0.00246359,0.00006722575,0.0006802262],"category_scores_gemma":[0.0001949247,0.0002813223,0.00003455929,0.002220432,0.001653237,0.001048291,0.0007518057,0.0001284472,0.001030102],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001531178,"about_ca_system_score_gemma":0.0001408,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002242782,"about_ca_topic_score_gemma":0.00003186059,"domain_scores_codex":[0.9953125,0.00005978258,0.0007271584,0.001208336,0.001906391,0.0007858498],"domain_scores_gemma":[0.9975438,0.0001598081,0.0004820008,0.001272266,0.0003120032,0.0002301777],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001832564,0.0003909006,0.0003785643,0.00003389632,0.000002484708,0.00000359437,0.002672945,0.002099656,0.9935361,0.0003617736,0.0001430507,0.0003587178],"study_design_scores_gemma":[0.0005274964,0.0001308904,0.00194674,0.00002015343,0.0000229088,0.00001446499,0.001165164,0.002024096,0.993476,0.0002274276,0.00008649383,0.0003581538],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889288,0.00005623247,0.0006151295,0.00006286371,0.0007143346,0.0007052988,0.00002014405,0.0001661021,0.008731121],"genre_scores_gemma":[0.9930353,0.000008801603,0.006619991,0.00007345414,0.00003714284,0.00002563255,0.00000356164,0.00002001218,0.000176152],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008554969,"threshold_uncertainty_score":0.9999639,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01868619803947847,"score_gpt":0.2546844549277792,"score_spread":0.2359982568883008,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}