{"id":"W2166328853","doi":"10.1002/chin.200338100","title":"Synthesis of 4‐(5‐Iodo‐3‐Methylpyrazolyl) Phenylsulfonamide (VIII) and Its Elaboration to a COX II Inhibitor Library by Solution‐Phase Suzuki Coupling Using Pd/C as a Solid‐Supported Catalyst.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":3,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Elaboration; Catalysis; Coupling (piping); Combinatorial chemistry; Phase (matter); Solid-phase synthesis; Organic chemistry; Biochemistry; Metallurgy; Humanities","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001384591,0.0004144381,0.0003547753,0.000283156,0.0001550832,0.0002300869,0.0004460868,0.0002052171,0.002451123],"category_scores_gemma":[0.0001430001,0.0002029368,0.0002756155,0.0002564518,0.000142167,0.0001539858,0.0002073706,0.0003885944,0.001331856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000292658,"about_ca_system_score_gemma":0.0004851642,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007963679,"about_ca_topic_score_gemma":0.001086966,"domain_scores_codex":[0.9999223,0.00001226179,0.000005412182,0.00001488189,0.00001767116,0.00002762697],"domain_scores_gemma":[0.9999572,0.000005297774,0.000007287135,0.000006025683,0.000007037263,0.00001716948],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002546881,0.00008810913,0.0001354671,0.0001597829,0.00002650011,0.0002864341,0.00005386553,0.0008535389,0.9763775,0.000695487,0.0008217912,0.02024676],"study_design_scores_gemma":[0.00005261379,0.0009955937,0.0009293393,0.000008143415,0.00003867683,0.0003385085,0.00001528525,0.000677054,0.9804516,0.0001113085,0.01636817,0.00001366936],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9040349,0.006336908,0.06151917,0.0003733124,0.0002053002,0.0005329183,0.004262718,0.001077496,0.0216572],"genre_scores_gemma":[0.9512483,0.004245037,0.02418658,0.00008636171,0.00003623902,0.0002166426,0.003622628,0.00007074012,0.01628743],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002451123,"threshold_uncertainty_score":0.008199811,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008773389390606469,"score_gpt":0.2532477500223018,"score_spread":0.2444743606316953,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}