{"id":"W2166882530","doi":"10.1139/v03-149","title":"Electroreduction of 1-methyl 5-nitroindole, 5-nitrobenzofurane, and 5-nitrobenzothiophene in acidic and basic hydroorganic media: Generation and trapping of iminoquinone-type intermediates and electrosynthesis of ring-substituted amino derivatives","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Regioselectivity; Electrosynthesis; Nucleophile; Cycloaddition; Electrolysis; Cyclopentadiene; Methanol; Medicinal chemistry; Ring (chemistry); Organic chemistry; Electrolyte; Catalysis; Electrochemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001184772,0.0003610401,0.0001302845,0.0001881923,0.0001420029,0.0001062358,0.0002175965,0.0001798974,0.001374065],"category_scores_gemma":[0.0001507272,0.0001346169,0.00009566572,0.0001477246,0.0001961473,0.0001929705,0.000131229,0.0002703307,0.0003029029],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002040887,"about_ca_system_score_gemma":0.0001551446,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001022801,"about_ca_topic_score_gemma":0.002352269,"domain_scores_codex":[0.9999378,0.000007418072,0.000002395426,0.00001182906,0.00002652943,0.00001405379],"domain_scores_gemma":[0.9999341,0.00002015689,0.00001469138,0.000004372294,0.00001514751,0.00001163434],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002336804,0.000002534022,0.00002289319,0.00001359345,0.000001163035,0.00001914433,0.00001275795,0.00002534437,0.999216,0.00002830825,0.000007038273,0.0006278606],"study_design_scores_gemma":[0.00000341387,0.00006466885,0.0005326204,0.000001053315,0.00000313197,0.00004477802,0.00001129555,0.0001007253,0.9988847,0.00001287297,0.0003395511,0.000001252562],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913495,0.001081482,0.004704351,0.00006712956,0.00001501523,0.00002300422,0.00009679156,0.00006518015,0.002597609],"genre_scores_gemma":[0.9922678,0.0009258875,0.002722117,0.00002184834,0.000006975621,0.0000135865,0.0001788877,0.00001985307,0.003843037],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001374065,"threshold_uncertainty_score":0.00459671,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01936643489291843,"score_gpt":0.2149212153612352,"score_spread":0.1955547804683167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}