{"id":"W2166882530","doi":"10.1139/v03-149","title":"Electroreduction of 1-methyl 5-nitroindole, 5-nitrobenzofurane, and 5-nitrobenzothiophene in acidic and basic hydroorganic media: Generation and trapping of iminoquinone-type intermediates and electrosynthesis of ring-substituted amino derivatives","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Regioselectivity; Electrosynthesis; Nucleophile; Cycloaddition; Electrolysis; Cyclopentadiene; Methanol; Medicinal chemistry; Ring (chemistry); Organic chemistry; Electrolyte; Catalysis; Electrochemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003916959,0.0001797134,0.0004787508,0.000155835,0.00004574247,0.00001809747,0.00008037392,0.0001946775,0.0000963385],"category_scores_gemma":[0.001215468,0.0001645027,0.00004074947,0.0001878704,0.000427554,0.0001322231,0.000009730815,0.0002228514,2.583622e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006338038,"about_ca_system_score_gemma":0.0003071461,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001866621,"about_ca_topic_score_gemma":0.000530605,"domain_scores_codex":[0.9987518,0.00006308504,0.0006279584,0.0002002896,0.0001425289,0.0002143139],"domain_scores_gemma":[0.9987496,0.0002296297,0.0005375074,0.00009515682,0.0001855763,0.000202504],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000561158,0.00002270005,0.01730737,0.0002599932,0.00005850708,0.000004156115,0.0004177946,0.00000497175,0.9793995,0.00002129826,0.000002288245,0.002445316],"study_design_scores_gemma":[0.000653911,0.00006968812,0.01430028,0.0002443089,0.00007788806,0.0001675203,0.0006113193,0.000155201,0.9832241,0.0003558355,0.000006581492,0.0001333779],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932304,0.006508442,0.00001519157,0.00005827277,0.00002385679,0.00004723301,0.00001199117,0.000002391493,0.0001022],"genre_scores_gemma":[0.9985861,0.001017252,0.0003007753,0.000006479009,0.00006286325,0.000001757193,0.000008619403,0.00001221437,0.000003940064],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00549119,"threshold_uncertainty_score":0.6708227,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01936643489291843,"score_gpt":0.2149212153612352,"score_spread":0.1955547804683167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}