{"id":"W2167358549","doi":"10.3109/10409238.2011.618220","title":"RNA and DNA complexes with hemin [Fe(III) heme] are efficient peroxidases and peroxygenases: how do they do it and what does it mean?","year":2011,"lang":"en","type":"review","venue":"Critical Reviews in Biochemistry and Molecular Biology","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":161,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hemin; Peroxidase; Heme; Porphyrin; DNA; Nucleic acid; Guanine; G-quadruplex; Biochemistry; Chemistry; RNA; Deoxyribozyme; Enzyme; Biology; Gene; Nucleotide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005656487,0.0009513376,0.002134064,0.0001101185,0.000163143,0.000262642,0.0002712978,0.0009243817,0.000003884623],"category_scores_gemma":[0.0007113432,0.0005965481,0.0002544277,0.000142034,0.001773079,0.0000163359,0.0005300344,0.0004375133,4.563898e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002491522,"about_ca_system_score_gemma":0.00007084407,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005961874,"about_ca_topic_score_gemma":0.00002952165,"domain_scores_codex":[0.9964435,0.0003720855,0.0007385647,0.001737137,0.0001174016,0.0005913465],"domain_scores_gemma":[0.9983039,0.0001552445,0.0003260685,0.0007430977,0.0001370093,0.0003347018],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001602748,0.0003506427,0.00003820026,0.02498342,0.0004611003,0.00017459,0.0001823147,3.454222e-8,0.3585376,0.001058449,0.0003129912,0.6137404],"study_design_scores_gemma":[0.0007385276,0.0007024624,0.000002449317,0.02986882,0.001327114,0.001107996,0.001605193,0.000002798038,0.1939013,0.0005600466,0.7681041,0.002079244],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.02389778,0.9746364,0.0002214867,0.0003504156,0.00003402453,0.0006516168,0.000102637,0.00002002316,0.00008558226],"genre_scores_gemma":[0.09207258,0.90522,0.001715332,0.0004550765,0.00009695982,0.0001124625,0.0002311693,0.00005015633,0.00004624735],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.7677911,"threshold_uncertainty_score":0.9996486,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02525805565738724,"score_gpt":0.3384463622784165,"score_spread":0.3131883066210293,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}