{"id":"W2167593811","doi":"10.1002/cjce.22340","title":"Application of irreversible thermodynamics to the solvent diffusion in an amorphous glassy polymer: A comprehensive model for drying of toluene‐poly(methyl methacrylate) coatings","year":2015,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Thermodynamics; Toluene; Diffusion; Materials science; Polymer; Methyl methacrylate; Solvent; Work (physics); Glass transition; Amorphous solid; Evaporation; Polymer chemistry; Physical chemistry; Chemistry; Organic chemistry; Composite material; Copolymer; Physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003224048,0.0001500295,0.0003069731,0.0001690548,0.00002428157,0.00001500005,0.0004310647,0.00008470074,8.348103e-7],"category_scores_gemma":[0.00006289959,0.0001158174,0.00009907694,0.0002492167,0.00003919934,0.0001000852,0.00002414936,0.0002435067,2.402347e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002855848,"about_ca_system_score_gemma":0.0001749669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001003213,"about_ca_topic_score_gemma":0.0007311716,"domain_scores_codex":[0.9990156,0.0000158262,0.0004365349,0.00008891177,0.0001750689,0.0002680184],"domain_scores_gemma":[0.9990752,0.0001187181,0.0001277716,0.0002293926,0.0001484242,0.0003004983],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00002267911,0.000006695261,0.00003036724,0.00002849738,0.00001968432,9.718416e-7,0.00130747,0.5475461,0.4501108,0.0002764654,0.000005076203,0.0006451897],"study_design_scores_gemma":[0.0004143065,0.00003687978,0.00003014502,0.00006839091,0.00003090748,0.00001383981,0.00009188415,0.9267455,0.07205551,0.0003733966,0.00002862079,0.0001105652],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8642683,0.000521897,0.134725,0.0001165612,0.0001104044,0.0002047789,0.00002662759,0.00001140726,0.00001495799],"genre_scores_gemma":[0.9975587,0.000002818102,0.002296198,0.00002713913,0.00005819962,0.00001026393,0.000004220105,0.00004017049,0.000002352464],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3791994,"threshold_uncertainty_score":0.4722897,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01781223975333948,"score_gpt":0.2270273063068819,"score_spread":0.2092150665535424,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}