{"id":"W2167818348","doi":"10.1002/cctc.201100422","title":"Heterogeneous versus Homogeneous Palladium Catalysts for Cross‐Coupling Reactions","year":2012,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":306,"is_retracted":false,"has_abstract":true,"ca_institutions":"SiliCycle (Canada)","funders":"Università degli Studi di Palermo","keywords":"Palladium; Catalysis; Homogeneous; Leaching (pedology); Coupling reaction; Heterogeneous catalysis; Homogeneous catalysis; Chemistry; Coupling (piping); Materials science; Chemical engineering; Combinatorial chemistry; Organic chemistry; Metallurgy; Thermodynamics; Environmental science; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008467347,0.0005553084,0.0003481033,0.0007266183,0.000183711,0.0007856704,0.000924589,0.0004621699,0.001723202],"category_scores_gemma":[0.0005723196,0.0003158648,0.0003264666,0.0004239793,0.0002939785,0.0006417968,0.0004170412,0.0008077225,0.0006580396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003323646,"about_ca_system_score_gemma":0.0001369482,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003674846,"about_ca_topic_score_gemma":0.0009869683,"domain_scores_codex":[0.9994288,0.0001449816,0.00005351791,0.0001336724,0.0001536158,0.00008548304],"domain_scores_gemma":[0.9998018,0.00006814596,0.00002861572,0.00003856425,0.00003310238,0.000029701],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002172004,0.0001400638,0.0002413167,0.0003341782,0.00006366509,0.0001128641,0.00003701336,0.001252669,0.9839385,0.001930294,0.0002147933,0.01151736],"study_design_scores_gemma":[0.00001805408,0.0002868002,0.0002870133,0.000009164932,0.00005153055,0.00005811704,0.00001476205,0.001400681,0.9955631,0.0001239908,0.002180416,0.000006361897],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9023249,0.02250643,0.05851586,0.0002204858,0.0002587467,0.0002323969,0.0003806966,0.0002621977,0.01529832],"genre_scores_gemma":[0.9826571,0.00489444,0.008839263,0.00007655779,0.00005281387,0.0000455426,0.0002803775,0.00004572735,0.003108148],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001723202,"threshold_uncertainty_score":0.005764663,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04012405404584818,"score_gpt":0.3211033299716086,"score_spread":0.2809792759257604,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}