{"id":"W2167895469","doi":"10.1002/anie.201006715","title":"In Vivo Solid‐Phase Microextraction: Capturing the Elusive Portion of Metabolome","year":2011,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metabolomics and Mass Spectrometry Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":153,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Solid-phase microextraction; Metabolome; Ultrafiltration (renal); Chromatography; Computer science; Phase (matter); Sampling (signal processing); Chemistry; Metabolomics; Mass spectrometry; Gas chromatography–mass spectrometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000174234,0.0001011264,0.0001186983,0.00007835234,0.00003821309,0.000007984222,0.000150262,0.00007051916,0.0002859688],"category_scores_gemma":[0.00008400594,0.00008226902,0.00008220446,0.00008048836,0.00006619127,0.00001938706,0.00006488067,0.00008125234,0.000003008353],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002312618,"about_ca_system_score_gemma":0.00002159442,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008255186,"about_ca_topic_score_gemma":0.00004839259,"domain_scores_codex":[0.9992889,0.00001513355,0.0002542922,0.0001896626,0.0001395199,0.0001124536],"domain_scores_gemma":[0.9994913,0.0000102976,0.0001865228,0.0001373788,0.0001520532,0.00002250232],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001135156,0.0001400053,0.0002834967,0.000005631295,0.00009539146,0.000003335505,0.0001615173,0.000003185653,0.9947786,0.000602593,0.003708637,0.0001040609],"study_design_scores_gemma":[0.0005751586,0.00006271634,0.00159903,0.000008328033,0.00002175614,0.00001676067,0.0002216677,0.000006184293,0.9773384,0.0007286814,0.01933744,0.0000838732],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9764358,0.000821004,0.004887783,0.0007777003,0.001919998,0.0001948747,0.0001358216,0.000009425142,0.01481758],"genre_scores_gemma":[0.9975278,0.0005956457,0.0002615059,0.0001814532,0.0008214263,0.0000333536,0.0001049435,0.000009061651,0.0004648389],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02109196,"threshold_uncertainty_score":0.3354833,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01961369408263061,"score_gpt":0.2980490022766077,"score_spread":0.2784353081939772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}