{"id":"W2167895469","doi":"10.1002/anie.201006715","title":"In Vivo Solid‐Phase Microextraction: Capturing the Elusive Portion of Metabolome","year":2011,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metabolomics and Mass Spectrometry Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":153,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Solid-phase microextraction; Metabolome; Ultrafiltration (renal); Chromatography; Computer science; Phase (matter); Sampling (signal processing); Chemistry; Metabolomics; Mass spectrometry; Gas chromatography–mass spectrometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000268272,0.0005678502,0.0003818643,0.0002439451,0.0002761653,0.0004979078,0.0003551108,0.0005593939,0.001529999],"category_scores_gemma":[0.000306277,0.0002259726,0.0002602959,0.0002025191,0.0003527363,0.0004737795,0.0003084063,0.001017143,0.001228413],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002149082,"about_ca_system_score_gemma":0.0003216432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003713362,"about_ca_topic_score_gemma":0.001489003,"domain_scores_codex":[0.9998106,0.00003198489,0.000007487473,0.00006699676,0.00005758032,0.0000252803],"domain_scores_gemma":[0.9997781,0.00009541302,0.0000382975,0.00003878887,0.00002719253,0.00002231559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002759129,0.000007323832,0.0000658918,0.00001928999,0.000002280475,0.00001148637,0.000005211707,0.0000143298,0.9982546,0.00004969692,0.0000812303,0.001461109],"study_design_scores_gemma":[0.000003693328,0.00005719872,0.0006879234,0.000002682194,0.00000686154,0.00009230107,0.000007629799,0.0005623935,0.9960227,0.0001083432,0.002443894,0.000004303693],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4981659,0.004724557,0.4818822,0.001442755,0.0005740772,0.0003078272,0.004152441,0.001383057,0.007367263],"genre_scores_gemma":[0.7237327,0.008057578,0.2393531,0.0008458899,0.0002382324,0.0003335306,0.004822623,0.0003233473,0.02229305],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001529999,"threshold_uncertainty_score":0.00511831,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01961369408263061,"score_gpt":0.2980490022766077,"score_spread":0.2784353081939772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}