{"id":"W2168029425","doi":"10.1002/anie.201108956","title":"From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":290,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"","keywords":"Ruthenium; Osmium; Catalysis; Chemistry; Dimer; Organic chemistry; Ethanol; Hydrogen; Alcohol oxidation; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001351975,0.0004892235,0.0002848434,0.0003361177,0.0001574154,0.0004124333,0.0004233291,0.0003330806,0.00309439],"category_scores_gemma":[0.0002122669,0.0002785425,0.0003985222,0.0002833469,0.0002878705,0.001061546,0.0006168678,0.0008684318,0.001652807],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002779069,"about_ca_system_score_gemma":0.0001871237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007056214,"about_ca_topic_score_gemma":0.0009011285,"domain_scores_codex":[0.9998745,0.00001356703,0.000009882041,0.00002091805,0.00004187359,0.00003925554],"domain_scores_gemma":[0.9999646,0.000004743597,0.000006981665,0.000009636095,0.000007500491,0.000006436211],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000359801,0.0001033189,0.0003408351,0.0005521081,0.0000541825,0.0005245061,0.0001985409,0.0009385805,0.9433489,0.01299686,0.00259206,0.03799034],"study_design_scores_gemma":[0.00002330079,0.0001618053,0.0001515163,0.00002309298,0.00002088082,0.0002030662,0.00003798257,0.0005781389,0.9804205,0.001097336,0.01726538,0.00001700519],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8758143,0.01561,0.02028708,0.001742142,0.000760507,0.00006911781,0.0005319019,0.0009193483,0.08426552],"genre_scores_gemma":[0.9699045,0.006125221,0.004293624,0.0003126354,0.0000557791,0.00001816133,0.0003353919,0.0001477318,0.01880707],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00309439,"threshold_uncertainty_score":0.01035172,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01155500115323188,"score_gpt":0.2409942125686894,"score_spread":0.2294392114154575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}