{"id":"W2168195923","doi":"10.1021/ac050564r","title":"Thermally Assisted Hydrolysis and Methylation of Purified Tannins from Plants","year":2005,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Fermentation and Sensory Analysis","field":"Agricultural and Biological Sciences","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"Natural Resources Canada; Canadian Forest Service","funders":"","keywords":"Chemistry; Tetramethylammonium hydroxide; Proanthocyanidin; Hydrolysis; Gallic acid; Hydroxylation; Solvolysis; Tannin; Condensed tannin; Methylation; Cleavage (geology); Ring (chemistry); Acid hydrolysis; Alkaline hydrolysis; Organic chemistry; Stereochemistry; Polyphenol; Food science; Biochemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002441087,0.0005615925,0.0003259457,0.0003170874,0.0001968611,0.0001408303,0.000174739,0.0002528317,0.0006537458],"category_scores_gemma":[0.0003008962,0.0002192676,0.0003809675,0.0003337318,0.0001757927,0.0001881884,0.0001385471,0.000579264,0.0002702054],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002081135,"about_ca_system_score_gemma":0.0002299869,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001856848,"about_ca_topic_score_gemma":0.003050599,"domain_scores_codex":[0.9998395,0.00003437774,0.00001184332,0.00005167068,0.00003363676,0.00002895393],"domain_scores_gemma":[0.9998312,0.00004835318,0.00003669364,0.00002440425,0.00004043352,0.00001891517],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002967575,0.000002111819,0.00008055334,0.00001325522,0.000004152963,0.000007627165,0.0000100484,0.00002436448,0.9994128,0.000004308411,0.00000358973,0.0004075142],"study_design_scores_gemma":[0.000007055529,0.0001860396,0.01196396,0.00000686387,0.00002976949,0.0001546615,0.00003423384,0.0006757813,0.9859239,0.00003619826,0.0009731321,0.000008448214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9857188,0.001868151,0.01012756,0.00005355478,0.00001514898,0.00007990209,0.0009589042,0.00007136222,0.00110666],"genre_scores_gemma":[0.9723502,0.00150186,0.01881334,0.00007866997,0.00002088596,0.0001032831,0.003498429,0.00006541074,0.003567952],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001856848,"threshold_uncertainty_score":0.003692091,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02436118768027727,"score_gpt":0.2398001090769442,"score_spread":0.2154389213966669,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}