{"id":"W2168556124","doi":"10.1021/jo049874k","title":"Addition of Bifunctional Organoboron Reagents to Strained Alkenes. Carbon−Carbon Bond Formation with Rh(I) Catalysis in Aqueous Media","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Transmetalation; Bifunctional; Catalysis; Rhodium; Steric effects; Reagent; Olefin fiber; Aqueous solution; Ligand (biochemistry); Organic chemistry; Combinatorial chemistry; Photochemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004144901,0.000217493,0.0003504015,0.0000917545,0.00006421164,0.00002442836,0.0003365049,0.0001503202,0.0006707975],"category_scores_gemma":[0.000427646,0.0001709948,0.00007928202,0.0005440754,0.0001122473,0.0001428869,0.00005584739,0.0004475255,0.000003198684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00115736,"about_ca_system_score_gemma":0.000481349,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000147928,"about_ca_topic_score_gemma":0.0002127218,"domain_scores_codex":[0.9981746,0.000002457012,0.000750631,0.0001623322,0.0006453156,0.000264685],"domain_scores_gemma":[0.9982493,0.0001468751,0.0006984472,0.0004190729,0.0003331889,0.0001531493],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003338283,0.0001897175,0.0002697817,0.0001080187,0.0001007615,0.00002470013,0.002162303,0.0009226573,0.9956062,0.000001045608,0.00003435927,0.0002465711],"study_design_scores_gemma":[0.001769273,0.00004478639,0.0009483722,0.0002467022,0.000176407,0.001108217,0.00260063,0.00006523842,0.9926673,0.0001780668,0.00001914603,0.0001758715],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989806,0.0001108333,0.00009177376,0.0003004168,0.0000650075,0.00005690934,0.0000344666,0.00002229238,0.0003376814],"genre_scores_gemma":[0.9994136,0.00003932084,0.00006655727,0.00001711805,0.0002627334,0.000004528647,0.00009155947,0.0000394512,0.00006509325],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002938967,"threshold_uncertainty_score":0.7344763,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007040960147740512,"score_gpt":0.2082504216801732,"score_spread":0.2012094615324327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}