{"id":"W2168802844","doi":"10.1002/1521-3773(20020301)41:5<799::aid-anie799>3.0.co;2-s","title":"Carbonyltris(trifluoromethyl)borane, (CF3)3BCO, An Unusual Boron Carbonyl This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie (D.F.G), Merck KGaA, Darmstadt, and the Heinrich Hertz Stiftung (Grant to F.A.)","year":2002,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Borane; Chemistry; Trifluoromethyl; Boron; Electrophile; Medicinal chemistry; Carbon atom; Hydrolysis; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008682514,0.0005999699,0.0004567859,0.00009993761,0.0006882133,0.000408553,0.001298953,0.0005895108,0.002419456],"category_scores_gemma":[0.0003628799,0.0003501287,0.000231929,0.0007111479,0.0004713459,0.000410501,0.0002989512,0.001537665,0.00003864975],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002884672,"about_ca_system_score_gemma":0.00008661122,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009652084,"about_ca_topic_score_gemma":0.0000525472,"domain_scores_codex":[0.9964263,0.0001028143,0.0007781229,0.0007761672,0.001224148,0.0006924327],"domain_scores_gemma":[0.9974535,0.0006242594,0.000373112,0.0008440576,0.0004299046,0.0002751343],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001116316,0.0004942283,0.0007882398,0.0000637296,0.001940766,0.0000508472,0.006234268,0.0000683855,0.3770392,0.001233755,0.6043541,0.006616178],"study_design_scores_gemma":[0.003927364,0.00006649658,0.000110235,0.0001153677,0.0004193741,0.0001079236,0.001195533,0.001120129,0.8346753,0.0004032473,0.1572503,0.0006087137],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8212839,0.00902041,0.0003783517,0.0500805,0.002473563,0.001138543,0.000522904,0.0004240352,0.1146778],"genre_scores_gemma":[0.9835101,0.0006902501,0.00005460914,0.001664925,0.002244968,0.0002441984,0.0007326937,0.00009956116,0.01075867],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4576361,"threshold_uncertainty_score":0.9998951,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01433477920120708,"score_gpt":0.2288209431559803,"score_spread":0.2144861639547732,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}