{"id":"W2168802844","doi":"10.1002/1521-3773(20020301)41:5<799::aid-anie799>3.0.co;2-s","title":"Carbonyltris(trifluoromethyl)borane, (CF3)3BCO, An Unusual Boron Carbonyl This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie (D.F.G), Merck KGaA, Darmstadt, and the Heinrich Hertz Stiftung (Grant to F.A.)","year":2002,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Borane; Chemistry; Trifluoromethyl; Boron; Electrophile; Medicinal chemistry; Carbon atom; Hydrolysis; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001820251,0.0002952331,0.0001897509,0.0002714337,0.0003134876,0.0001792389,0.0002708688,0.0003950169,0.002458286],"category_scores_gemma":[0.0001182177,0.0001528943,0.0001212716,0.0001742665,0.0003122334,0.0002556498,0.0001832051,0.0002461563,0.0007765563],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003316967,"about_ca_system_score_gemma":0.0003036964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006512453,"about_ca_topic_score_gemma":0.001963801,"domain_scores_codex":[0.9999139,0.00001001797,0.000005580056,0.00002329946,0.00002046846,0.00002663185],"domain_scores_gemma":[0.9999206,0.00001057115,0.00002043415,0.000007967161,0.00000861164,0.00003191975],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001388385,0.00001161144,0.0001420924,0.0001317461,0.000003860511,0.0001860975,0.00002189002,0.0000525841,0.9953372,0.0009504826,0.0002790044,0.002744556],"study_design_scores_gemma":[0.00008204523,0.0005736923,0.001049649,0.00001362112,0.00001379577,0.001496025,0.000031125,0.0001635657,0.9722796,0.0002875556,0.02399307,0.00001629827],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9491311,0.008955978,0.01286752,0.0008491164,0.0004122523,0.0001400036,0.001753787,0.0003298634,0.02556027],"genre_scores_gemma":[0.9792958,0.002341525,0.01130776,0.0001700731,0.0000742573,0.00005278875,0.0009360073,0.00003398029,0.005787656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002458286,"threshold_uncertainty_score":0.008223772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01433477920120708,"score_gpt":0.2288209431559803,"score_spread":0.2144861639547732,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}