{"id":"W2168866252","doi":"10.1002/anie.201410875","title":"Nickel‐Catalyzed Monoarylation of Ammonia","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":131,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Ammonia; Catalysis; Nickel; Electrophile; Bromide; Chemistry; Chloride; Aryl; Combinatorial chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001726264,0.0004411896,0.0002365692,0.000207664,0.0002036593,0.0001954489,0.0003854925,0.0002484283,0.001272445],"category_scores_gemma":[0.0002267031,0.0001643543,0.0001866889,0.0001885997,0.0001304232,0.0002923835,0.000485113,0.0003769142,0.0006158947],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003130725,"about_ca_system_score_gemma":0.0003607119,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001033764,"about_ca_topic_score_gemma":0.003384518,"domain_scores_codex":[0.9998015,0.00002125709,0.00002437301,0.0000392401,0.00004996545,0.00006386096],"domain_scores_gemma":[0.9999431,0.000006716491,0.0000151159,0.00001062743,0.00001473173,0.000009625417],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008612952,0.00002455597,0.0001502706,0.0001273305,0.00001370327,0.0001274453,0.00005402878,0.000132653,0.9918527,0.000738581,0.0001883876,0.006504284],"study_design_scores_gemma":[0.0000044946,0.00006846186,0.0003393332,0.000004128695,0.000007230238,0.0001014077,0.000008298621,0.0002961438,0.9971581,0.00003246947,0.00197575,0.000004210504],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.962779,0.001689751,0.01130524,0.0001561651,0.0001092497,0.00009572271,0.0003781641,0.0002748666,0.0232119],"genre_scores_gemma":[0.9912968,0.0008925167,0.003493295,0.0000330653,0.00001290535,0.00003628542,0.0002491958,0.00002752038,0.003958538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001272445,"threshold_uncertainty_score":0.004256725,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02845639625418497,"score_gpt":0.2888568810789054,"score_spread":0.2604004848247205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}