{"id":"W2168866252","doi":"10.1002/anie.201410875","title":"Nickel‐Catalyzed Monoarylation of Ammonia","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":131,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Ammonia; Catalysis; Nickel; Electrophile; Bromide; Chemistry; Chloride; Aryl; Combinatorial chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001409812,0.0001307071,0.0001450601,0.00009081059,0.00003734211,0.0000406484,0.0002151065,0.0001209847,0.0005645876],"category_scores_gemma":[0.0003407082,0.0001441746,0.0001008886,0.0001278611,0.00009317807,0.0003679204,0.00006102344,0.000142042,0.00009691875],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000300258,"about_ca_system_score_gemma":0.00009418988,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002405356,"about_ca_topic_score_gemma":0.0000264217,"domain_scores_codex":[0.9988139,5.363017e-7,0.0003418204,0.000234165,0.0004750919,0.0001344694],"domain_scores_gemma":[0.9988728,0.00007635555,0.0002423044,0.000248644,0.0004609351,0.00009896477],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000933917,0.0001498788,0.001503431,0.00002556278,0.000071547,0.00000382218,0.0002408789,0.0001043642,0.988066,0.0002452089,0.008809062,0.0006868188],"study_design_scores_gemma":[0.0009042318,0.000007275127,0.0003942189,0.0000522266,0.00003045325,0.00002472385,0.0002047768,0.0006084729,0.9896776,0.001234067,0.006726847,0.0001351143],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9801576,0.00006987432,0.001059211,0.0005099257,0.001149449,0.00005192209,0.0002361063,0.0001231881,0.01664273],"genre_scores_gemma":[0.994498,0.00001932559,0.0001574829,0.00002249451,0.00116491,0.00002708366,0.002492562,0.00002133153,0.001596821],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01504591,"threshold_uncertainty_score":0.6181839,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02845639625418497,"score_gpt":0.2888568810789054,"score_spread":0.2604004848247205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}