{"id":"W2169071968","doi":"10.1039/b401039f","title":"Synthesis, structure and electrochemistry of ferrocene–peptide macrocycles","year":2004,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Ferrocene; Chemistry; Intramolecular force; Cysteamine; Peptide; Amide; Electrochemistry; Stereochemistry; Combinatorial chemistry; Redox; Ring (chemistry); Crystallography; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Electrode; Biochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002047826,0.0001824869,0.0001919065,0.00002491697,0.0001746261,0.0000168219,0.0001641781,0.0001686562,0.0008911027],"category_scores_gemma":[0.00001490778,0.0001944131,0.00008016694,0.0001327712,0.0001320062,0.00007583402,0.000005865515,0.0002510785,0.000003066868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005302299,"about_ca_system_score_gemma":0.00007798769,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003407601,"about_ca_topic_score_gemma":0.00002222506,"domain_scores_codex":[0.999102,0.000002866778,0.0002446072,0.0002953356,0.0001310156,0.0002242019],"domain_scores_gemma":[0.999402,0.00005202153,0.0000832322,0.0002981705,0.00004584845,0.0001187355],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000019261,0.00008510482,0.00007787702,0.0002970252,0.00004205335,0.000001145001,0.0001212778,0.0003063285,0.9978536,0.0001505474,0.00001526835,0.001030515],"study_design_scores_gemma":[0.0003024515,0.000004376997,0.0001422805,0.00006670426,0.00007672854,0.00006975151,0.0002617081,0.00001874014,0.9967462,0.001324485,0.0008046956,0.0001819133],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908258,0.0002691496,0.004351837,0.0003026664,0.00001178398,0.00004025338,0.0003827779,0.0001023189,0.003713418],"genre_scores_gemma":[0.9981946,0.0001810377,0.001122942,0.00002395521,0.00004738747,0.00003759077,0.00005152751,0.00002274456,0.0003181799],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007368841,"threshold_uncertainty_score":0.9756949,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006675529672300767,"score_gpt":0.2206919337511619,"score_spread":0.2140164040788612,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}