{"id":"W2169263140","doi":"10.1016/s0022-328x(00)00732-4","title":"Some reactions of the platinum(II) carbene complex cis-dichloro(dimethylaminomethylene)(triphenylphosphine)platinum(II) and the X-ray crystal and molecular structures of the products trans-(CH2,P)-chloro(chloromethyl)(dimethylaminomethylene)(triphenylphosphine)platinum(II) and [1,2-bis(diphenylphosphino)ethane](dimethylaminomethylene)(triphenylphosphine)platinum(II) bis(hexafluorophosphate)","year":2001,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Phosphine; Triphenylphosphine; Carbene; Diphosphines; Medicinal chemistry; Platinum; Hexafluorophosphate; Methylene; Ligand (biochemistry); Oxidative addition; Trans effect; Crystal structure; Stereochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.005264468,0.003585576,0.006280732,0.0009242228,0.003549726,0.0004941014,0.005068049,0.001713154,0.00615573],"category_scores_gemma":[0.004437895,0.002483464,0.002728711,0.005911814,0.005880711,0.001493864,0.004720451,0.004218998,0.000002531445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007153322,"about_ca_system_score_gemma":0.001316417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001009033,"about_ca_topic_score_gemma":0.00006166958,"domain_scores_codex":[0.9813122,0.0006569907,0.007638386,0.00325826,0.004514956,0.002619179],"domain_scores_gemma":[0.9805291,0.002956405,0.008371623,0.004995125,0.001891606,0.001256121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001619436,0.001359284,0.001897883,0.001750232,0.004218764,0.00007180091,0.004983236,0.0004904644,0.9670362,0.000960847,0.0002714731,0.01534036],"study_design_scores_gemma":[0.01328398,0.0008280953,0.02810756,0.0008074015,0.005238926,0.001404373,0.003091397,0.000461977,0.9085927,0.005233431,0.02978577,0.003164403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9132672,0.07805781,0.000198969,0.003555845,0.0008862351,0.001735008,0.0009155931,0.0001808015,0.001202523],"genre_scores_gemma":[0.9809148,0.007442615,0.003201563,0.000366376,0.001200697,0.0001333975,0.0001666647,0.0005871289,0.005986772],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07061519,"threshold_uncertainty_score":0.9995828,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01078214079996135,"score_gpt":0.2098934275077561,"score_spread":0.1991112867077947,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}