{"id":"W2169672103","doi":"10.1002/chem.201204288","title":"H(OEt<sub>2</sub>)<sub>2</sub>[P(1,2‐O<sub>2</sub>C<sub>6</sub>Cl<sub>4</sub>)<sub>3</sub>]: Synthesis, Characterization, and Application as a Single‐Component Initiator for the Carbocationic Polymerization of Olefins","year":2013,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Isoprene; Styrene; Monomer; Chemistry; Isobutylene; Polymer chemistry; Polymerization; Hexacoordinate; Protonation; Ether; Nuclear magnetic resonance spectroscopy; Polystyrene; Acetonitrile; Diethyl ether; Dimer; Trimethylsilyl; Crystallography; Medicinal chemistry; Polymer; Stereochemistry; Copolymer; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.002127404,0.002472721,0.002372774,0.0006326565,0.002232116,0.001579853,0.002493266,0.0008648075,0.0002755795],"category_scores_gemma":[0.001452539,0.002495212,0.001512028,0.001871815,0.001095177,0.001451159,0.0009247451,0.00199073,0.0004642554],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00103765,"about_ca_system_score_gemma":0.000926792,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001364267,"about_ca_topic_score_gemma":0.00001822689,"domain_scores_codex":[0.987239,0.0008063845,0.004400618,0.00289723,0.002286683,0.002370053],"domain_scores_gemma":[0.9876218,0.001132891,0.004824418,0.003134559,0.001665373,0.001620924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002963232,0.001194965,0.000299977,0.00107621,0.001191371,0.00005255678,0.0006820339,0.00008467247,0.8741637,0.00003809094,0.0004108877,0.1205091],"study_design_scores_gemma":[0.002404935,0.0001638541,0.005967199,0.001031393,0.001932811,0.0008619768,0.0007779356,0.002788143,0.9795852,0.0001388513,0.001833603,0.002514158],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9858668,0.001840442,0.006804427,0.001461111,0.0004584238,0.001497233,0.0008369765,0.0005099976,0.0007245339],"genre_scores_gemma":[0.9868351,0.005726198,0.0001087326,0.0004637862,0.002937664,0.0007204472,0.00228312,0.0008860331,0.00003896796],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.117995,"threshold_uncertainty_score":0.9994566,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009762829041967664,"score_gpt":0.1901640296389627,"score_spread":0.1804012005969951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}