{"id":"W2169914520","doi":"10.1039/b405715e","title":"The reaction of Li[Al(OR)<sub>4</sub>] R = OC(CF<sub>3</sub>)<sub>2</sub>Ph, OC(CF<sub>3</sub>)<sub>3</sub>with NO/NO<sub>2</sub>giving NO[Al(OR)<sub>4</sub>], Li[NO<sub>3</sub>] and N<sub>2</sub>O. The synthesis of NO[Al(OR)<sub>4</sub>] from Li[Al(OR)<sub>4</sub>] and NO[SbF<sub>6</sub>] in sulfur dioxide solution","year":2004,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Disproportionation; Chemistry; Lattice energy; Yield (engineering); Thermal decomposition; Crystal structure; Nuclear chemistry; Inorganic chemistry; Crystallography; Catalysis; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001257106,0.0003832812,0.0003006129,0.000209079,0.0001827767,0.0001652655,0.0004475984,0.0002873355,0.001784742],"category_scores_gemma":[0.0002373382,0.0001220975,0.000280536,0.0001619446,0.0001409398,0.0002265922,0.0002395352,0.0002593224,0.0005601811],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000333473,"about_ca_system_score_gemma":0.000492524,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002257892,"about_ca_topic_score_gemma":0.005943672,"domain_scores_codex":[0.9998701,0.00001693322,0.00001062893,0.00003277892,0.00003914046,0.00003045127],"domain_scores_gemma":[0.9999582,0.000005453931,0.00001258908,0.000006845722,0.00001013732,0.000006739428],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002907719,0.00002207649,0.0004382966,0.0004874693,0.00002692463,0.0001661,0.00004093986,0.0004044328,0.9909068,0.0006712631,0.0002654108,0.006279406],"study_design_scores_gemma":[0.00001892954,0.0002361183,0.001253034,0.0000223209,0.00004202422,0.000392689,0.0000281099,0.0007652896,0.9859299,0.0001645711,0.01113246,0.0000145218],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9466423,0.004874304,0.01853429,0.0001601416,0.0004451383,0.0002701386,0.001061224,0.0004876925,0.02752474],"genre_scores_gemma":[0.9696056,0.001699008,0.009893801,0.00008921194,0.00002636047,0.0001020327,0.0006502602,0.00004704987,0.01788653],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002257892,"threshold_uncertainty_score":0.005970538,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008497641606560389,"score_gpt":0.2054751720647064,"score_spread":0.1969775304581461,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}