{"id":"W2169914520","doi":"10.1039/b405715e","title":"The reaction of Li[Al(OR)<sub>4</sub>] R = OC(CF<sub>3</sub>)<sub>2</sub>Ph, OC(CF<sub>3</sub>)<sub>3</sub>with NO/NO<sub>2</sub>giving NO[Al(OR)<sub>4</sub>], Li[NO<sub>3</sub>] and N<sub>2</sub>O. The synthesis of NO[Al(OR)<sub>4</sub>] from Li[Al(OR)<sub>4</sub>] and NO[SbF<sub>6</sub>] in sulfur dioxide solution","year":2004,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Disproportionation; Chemistry; Lattice energy; Yield (engineering); Thermal decomposition; Crystal structure; Nuclear chemistry; Inorganic chemistry; Crystallography; Catalysis; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.0108797,0.01672607,0.01509344,0.007725122,0.01215297,0.005022096,0.01041667,0.01234692,0.0002393662],"category_scores_gemma":[0.006397234,0.01540691,0.008031324,0.01610542,0.009941374,0.01111404,0.003326028,0.02207021,0.004814322],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01069221,"about_ca_system_score_gemma":0.009829644,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001600625,"about_ca_topic_score_gemma":0.0143395,"domain_scores_codex":[0.927889,0.005872847,0.01882518,0.01720214,0.01317646,0.01703435],"domain_scores_gemma":[0.9428341,0.01188905,0.0130544,0.01502828,0.009403706,0.007790518],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01754512,0.00775576,0.0007266082,0.004631108,0.008175042,0.002145099,0.00427952,0.00379164,0.8666918,0.0002630096,0.01511227,0.06888302],"study_design_scores_gemma":[0.02146059,0.004453879,0.003773723,0.009657431,0.008638695,0.004714467,0.004149153,0.006905397,0.911769,0.001269907,0.007046823,0.01616092],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9441692,0.006715228,0.005459763,0.004648315,0.01237777,0.01195354,0.007581925,0.005310215,0.00178404],"genre_scores_gemma":[0.8919094,0.08360858,0.0006901925,0.003187919,0.006371007,0.004799119,0.004106059,0.005171504,0.000156232],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07689335,"threshold_uncertainty_score":0.9995285,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008497641606560389,"score_gpt":0.2054751720647064,"score_spread":0.1969775304581461,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}