{"id":"W2170189436","doi":"10.1002/pola.22067","title":"Kinetics of methyl methacrylate and <i>n</i>‐butyl acrylate copolymerization mediated by 2‐cyanoprop‐2‐yl dithiobenzoate as a RAFT agent","year":2007,"lang":"en","type":"article","venue":"Journal of Polymer Science Part A Polymer Chemistry","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Raft; Copolymer; Polymer chemistry; Methyl methacrylate; Kinetics; Chain transfer; Monomer; Chemistry; Acrylate; Polymerization; Methacrylate; Reversible addition−fragmentation chain-transfer polymerization; Radical polymerization; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009494753,0.0005517773,0.0008360929,0.0002435988,0.0002296877,0.0001239493,0.0008863287,0.0003222582,0.0009288442],"category_scores_gemma":[0.0003254353,0.0004978842,0.0002371625,0.001032592,0.00124304,0.000807959,0.0002314248,0.0005069933,0.00000740114],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001224391,"about_ca_system_score_gemma":0.0002748139,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004084696,"about_ca_topic_score_gemma":0.000001444098,"domain_scores_codex":[0.9950076,0.00004129734,0.001845797,0.0006295407,0.001555019,0.0009207024],"domain_scores_gemma":[0.9955761,0.000268969,0.002373694,0.0005847171,0.0004096849,0.0007867628],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002077995,0.0002493403,0.0006415651,0.0001256658,0.0001080772,0.0000288515,0.0005606881,0.000001778604,0.9851741,0.00002437559,0.00006719963,0.01281052],"study_design_scores_gemma":[0.0009771618,0.00009364264,0.00005957293,0.0002233581,0.0001787385,0.0002300378,0.000555482,0.00008315001,0.9954624,0.00002366779,0.001611183,0.000501673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9702436,0.02478457,0.001534025,0.0003871974,0.0004445232,0.00007895353,0.0001183917,0.00004954562,0.002359242],"genre_scores_gemma":[0.9961624,0.0009478835,0.000146214,0.0002146693,0.0003569565,0.000005660891,0.00003299326,0.00007114979,0.002062103],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02591882,"threshold_uncertainty_score":0.9999844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007132443106195705,"score_gpt":0.2501681018274292,"score_spread":0.2430356587212334,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}